Back to homePhysics and Chemistry · 4th ESO A · Change subject
Start for free
ESO Y4A · Physics and Chemistry
Chemical change · Chemical reactions of interest

Neutralisation reactions

Heartburn is relieved with an antacid; soil that is too acidic is corrected with lime; acidic wastewater from a factory is treated with a base before it is discharged into the river. All three cases are the same type of chemical reaction: an acid meets a base and they "cancel" each other out.

Before you start, make sure you know: The chemical equation and how to balance it (3rd ESO)
Before you start, make sure you know: Solutions and concentration (2nd ESO)

Acids, bases and the pH scale

Lemon juice tastes sour and turns red cabbage extract red, while soap feels slippery to the touch and turns it green or blue: what chemical property explains why these two families of substances behave in such opposite ways?

pH scale from 0 to 14: acidic zone below 7, neutral point at 7 and basic zone above 7 neutral acidic basic 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Practice★☆☆Not started
Classify each of these substances as an acid, a base or a salt: a) $HNO_3$ (nitric acid) b) $KOH$ (potassium hydroxide) c) $NaCl$ (sodium chloride) d) $H_2SO_4$…

Classify each of these substances as an acid, a base or a salt:

  1. a) $HNO_3$ (nitric acid)
  2. b) $KOH$ (potassium hydroxide)
  3. c) $NaCl$ (sodium chloride)
  4. d) $H_2SO_4$ (sulfuric acid)
  5. e) $Ca(OH)_2$ (calcium hydroxide)
Solve
Practice★☆☆Not started
pH measures how acidic or basic a solution is. These are the positions of the four solutions on the pH scale: State whether each of these solutions is acidic, neutral or…

pH measures how acidic or basic a solution is. These are the positions of the four solutions on the pH scale:

pH 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 lemon juice crushed tomato pure water hand soap

State whether each of these solutions is acidic, neutral or basic:

  1. a) lemon juice, $pH = 2,5$
  2. b) pure water, $pH = 7$
  3. c) hand soap, $pH = 10$
  4. d) crushed tomato, $pH = 4,5$
Solve

The heart of neutralisation: $\text{H}^+ + \text{OH}^- \rightarrow \text{H}_2\text{O}$

If you mix concentrated hydrochloric acid with concentrated sodium hydroxide (two very corrosive substances that burn the skin), the resulting liquid no longer corrodes and, when the water evaporates, only common table salt is left: how can they cancel each other out so completely?

A proton H⁺ and a hydroxide ion OH⁻ join to form a neutral water molecule, with the oxygen at the vertex and the two hydrogens forming an angle of about 105° + H⁺ + O H OH⁻ O H H H₂O neutral, pH = 7
Practice★☆☆Not started
Complete the general scheme of a neutralisation reaction with the missing words: "An $\dots$ reacts with a $\dots$ to form a $\dots$ and $\dots$". Then give an example…

Complete the general scheme of a neutralisation reaction with the missing words: "An $\dots$ reacts with a $\dots$ to form a $\dots$ and $\dots$". Then give an example using the reaction between hydrochloric acid and sodium hydroxide.

Solve
Practice★☆☆Not started
In the laboratory, hydrochloric acid ($HCl$) is mixed with sodium hydroxide ($NaOH$) to form sodium chloride ($NaCl$), common salt, and water. Write the reaction…

In the laboratory, hydrochloric acid ($HCl$) is mixed with sodium hydroxide ($NaOH$) to form sodium chloride ($NaCl$), common salt, and water. Write the reaction equation and check by counting atoms that it is balanced.

Solve

Balancing neutralisations with more than one H or more than one OH

When the acid supplies more than one $\text{H}^+$ per molecule, or the base more than one $\text{OH}^-$, you need to balance carefully so that every $\text{H}^+$ ion finds its $\text{OH}^-$.

Practice★★☆Not started
Sulfuric acid ($H_2SO_4$) reacts with calcium hydroxide ($Ca(OH)2$) to form calcium sulfate ($CaSO_4$) and water. Write the equation and balance it; pay close attention…

Sulfuric acid ($H_2SO_4$) reacts with calcium hydroxide ($Ca(OH)_2$) to form calcium sulfate ($CaSO_4$) and water. Write the equation and balance it; pay close attention to how many water molecules are formed for each calcium sulfate.

Solve
Practice★★☆Not started
Write and balance the equation for the neutralisation between hydrochloric acid ($HCl$) and calcium hydroxide ($Ca(OH)2$), forming calcium chloride ($CaCl_2$) and water.

Write and balance the equation for the neutralisation between hydrochloric acid ($HCl$) and calcium hydroxide ($Ca(OH)_2$), forming calcium chloride ($CaCl_2$) and water.

Solve
Practice★★☆Not started
Write and balance the equation for the neutralisation of sulfuric acid ($H_2SO_4$) with sodium hydroxide ($NaOH$), forming sodium sulfate ($Na_2SO_4$) and water.

Write and balance the equation for the neutralisation of sulfuric acid ($H_2SO_4$) with sodium hydroxide ($NaOH$), forming sodium sulfate ($Na_2SO_4$) and water.

Solve

Antacids and the chemistry of the body

Two stomachs compared: on the left, with excess gastric acid and many H⁺, causing heartburn; on the right, after taking an antacid, the excess acid is neutralised to form water and some acid is still left for digestion. Heartburn: excess acid With antacid stomach H⁺ H⁺ H⁺ H⁺ H⁺ H⁺ H⁺ H⁺ H⁺ oesophagus H⁺ H⁺ OH⁻ H₂O H₂O H₂O + antacid (base) gastric acid (HCl) many H⁺ excess is neutralised acid left for digestion Mg(OH)₂ + 2 HCl → MgCl₂ + 2 H₂O
Practice★☆☆Not started
Gastric juice in the stomach contains hydrochloric acid. In cases of heartburn, antacids from the pharmacy, which contain bases such as magnesium hydroxide, relieve it.…

Gastric juice in the stomach contains hydrochloric acid. In cases of heartburn, antacids from the pharmacy, which contain bases such as magnesium hydroxide, relieve it. Explain, using the concept of neutralisation, how an antacid works in the stomach.

Solve
Practice★☆☆Not started
Litmus paper turns red in acidic conditions and blue in basic conditions. a) What colour will it turn in a solution of $HCl$? b) And in a solution of $NaOH$? c) We mix…

Litmus paper turns red in acidic conditions and blue in basic conditions.

  1. a) What colour will it turn in a solution of $HCl$?
  2. b) And in a solution of $NaOH$?
  3. c) We mix the two solutions in exact amounts for complete neutralisation: explain why the litmus paper no longer indicates acid or base in the resulting mixture.
Solve
Practice★☆☆Not started
Write the formula and name of the salt formed in each neutralization reaction: a) Hydrochloric acid ($HCl$) with potassium hydroxide ($KOH$). b) Nitric acid ($HNO_3$)…

Write the formula and name of the salt formed in each neutralization reaction:

  1. a) Hydrochloric acid ($HCl$) with potassium hydroxide ($KOH$).
  2. b) Nitric acid ($HNO_3$) with sodium hydroxide ($NaOH$).
Solve

Calculating with neutralisations

A stomach with 10 HCl particles (0,1 mol) and a glass of milk of magnesia with 5 Mg(OH)₂ particles (0,05 mol): each Mg(OH)₂ neutralises two HCl, so you divide by 2 Mg(OH)₂ neutralises HCl 0,1 mol HCl in the stomach ÷ 2 0,05 mol Mg(OH)₂ (milk of magnesia)
Practice★★☆Not started
Milk of magnesia is a suspension of magnesium hydroxide ($Mg(OH)2$) taken for heartburn. Its reaction with stomach acid is…

Milk of magnesia is a suspension of magnesium hydroxide ($Mg(OH)_2$) taken for heartburn. Its reaction with stomach acid is $Mg(OH)_2 + 2\ HCl \rightarrow MgCl_2 + 2\ H_2O$.

  1. a) How many moles of $HCl$ does $1\ \text{mol}$ of $Mg(OH)_2$ neutralise?
  2. b) If the stomach has an excess of $0,1\ \text{mol}$ of $HCl$, how many moles of $Mg(OH)_2$ are needed to neutralise it?
Solve
Practice★★★Not started
In a laboratory flask, there are $0,2\ \text{mol}$ of sulphuric acid ($H_2SO_4$). a) Write the balanced equation for its neutralisation with sodium hydroxide ($NaOH$),…

In a laboratory flask, there are $0,2\ \text{mol}$ of sulphuric acid ($H_2SO_4$).

  1. a) Write the balanced equation for its neutralisation with sodium hydroxide ($NaOH$), which produces sodium sulphate ($Na_2SO_4$) and water.
  2. b) Calculate how many moles of $NaOH$ are needed to neutralise all the acid.
  3. c) If we were to add only $0,2\ \text{mol}$ of $NaOH$, would the solution be acidic, neutral or basic? Justify your answer using stoichiometry.
Solve

Back to the start: Acidic wastewater from a factory is neutralised by adding a base before it is discharged; likewise, lime is a base that neutralises the acidity of the soil, just as an antacid neutralises the excess hydrochloric acid in the stomach.

Summary

See all the exercises in this section