Neutralisation reactions
Heartburn is relieved with an antacid; soil that is too acidic is corrected with lime; acidic wastewater from a factory is treated with a base before it is discharged into the river. All three cases are the same type of chemical reaction: an acid meets a base and they "cancel" each other out.
Acids, bases and the pH scale
Lemon juice tastes sour and turns red cabbage extract red, while soap feels slippery to the touch and turns it green or blue: what chemical property explains why these two families of substances behave in such opposite ways?
Classify each of these substances as an acid, a base or a salt: a) $HNO_3$ (nitric acid) b) $KOH$ (potassium hydroxide) c) $NaCl$ (sodium chloride) d) $H_2SO_4$…
Classify each of these substances as an acid, a base or a salt:
- a) $HNO_3$ (nitric acid)
- b) $KOH$ (potassium hydroxide)
- c) $NaCl$ (sodium chloride)
- d) $H_2SO_4$ (sulfuric acid)
- e) $Ca(OH)_2$ (calcium hydroxide)
pH measures how acidic or basic a solution is. These are the positions of the four solutions on the pH scale: State whether each of these solutions is acidic, neutral or…
pH measures how acidic or basic a solution is. These are the positions of the four solutions on the pH scale:
State whether each of these solutions is acidic, neutral or basic:
- a) lemon juice, $pH = 2,5$
- b) pure water, $pH = 7$
- c) hand soap, $pH = 10$
- d) crushed tomato, $pH = 4,5$
The heart of neutralisation: $\text{H}^+ + \text{OH}^- \rightarrow \text{H}_2\text{O}$
If you mix concentrated hydrochloric acid with concentrated sodium hydroxide (two very corrosive substances that burn the skin), the resulting liquid no longer corrodes and, when the water evaporates, only common table salt is left: how can they cancel each other out so completely?
Complete the general scheme of a neutralisation reaction with the missing words: "An $\dots$ reacts with a $\dots$ to form a $\dots$ and $\dots$". Then give an example…
Complete the general scheme of a neutralisation reaction with the missing words: "An $\dots$ reacts with a $\dots$ to form a $\dots$ and $\dots$". Then give an example using the reaction between hydrochloric acid and sodium hydroxide.
In the laboratory, hydrochloric acid ($HCl$) is mixed with sodium hydroxide ($NaOH$) to form sodium chloride ($NaCl$), common salt, and water. Write the reaction…
In the laboratory, hydrochloric acid ($HCl$) is mixed with sodium hydroxide ($NaOH$) to form sodium chloride ($NaCl$), common salt, and water. Write the reaction equation and check by counting atoms that it is balanced.
Balancing neutralisations with more than one H or more than one OH
When the acid supplies more than one $\text{H}^+$ per molecule, or the base more than one $\text{OH}^-$, you need to balance carefully so that every $\text{H}^+$ ion finds its $\text{OH}^-$.
Sulfuric acid ($H_2SO_4$) reacts with calcium hydroxide ($Ca(OH)2$) to form calcium sulfate ($CaSO_4$) and water. Write the equation and balance it; pay close attention…
Sulfuric acid ($H_2SO_4$) reacts with calcium hydroxide ($Ca(OH)_2$) to form calcium sulfate ($CaSO_4$) and water. Write the equation and balance it; pay close attention to how many water molecules are formed for each calcium sulfate.
Write and balance the equation for the neutralisation between hydrochloric acid ($HCl$) and calcium hydroxide ($Ca(OH)2$), forming calcium chloride ($CaCl_2$) and water.
Write and balance the equation for the neutralisation between hydrochloric acid ($HCl$) and calcium hydroxide ($Ca(OH)_2$), forming calcium chloride ($CaCl_2$) and water.
Write and balance the equation for the neutralisation of sulfuric acid ($H_2SO_4$) with sodium hydroxide ($NaOH$), forming sodium sulfate ($Na_2SO_4$) and water.
Write and balance the equation for the neutralisation of sulfuric acid ($H_2SO_4$) with sodium hydroxide ($NaOH$), forming sodium sulfate ($Na_2SO_4$) and water.
Antacids and the chemistry of the body
Gastric juice in the stomach contains hydrochloric acid. In cases of heartburn, antacids from the pharmacy, which contain bases such as magnesium hydroxide, relieve it.…
Gastric juice in the stomach contains hydrochloric acid. In cases of heartburn, antacids from the pharmacy, which contain bases such as magnesium hydroxide, relieve it. Explain, using the concept of neutralisation, how an antacid works in the stomach.
Litmus paper turns red in acidic conditions and blue in basic conditions. a) What colour will it turn in a solution of $HCl$? b) And in a solution of $NaOH$? c) We mix…
Litmus paper turns red in acidic conditions and blue in basic conditions.
- a) What colour will it turn in a solution of $HCl$?
- b) And in a solution of $NaOH$?
- c) We mix the two solutions in exact amounts for complete neutralisation: explain why the litmus paper no longer indicates acid or base in the resulting mixture.
Write the formula and name of the salt formed in each neutralization reaction: a) Hydrochloric acid ($HCl$) with potassium hydroxide ($KOH$). b) Nitric acid ($HNO_3$)…
Write the formula and name of the salt formed in each neutralization reaction:
- a) Hydrochloric acid ($HCl$) with potassium hydroxide ($KOH$).
- b) Nitric acid ($HNO_3$) with sodium hydroxide ($NaOH$).
Calculating with neutralisations
Milk of magnesia is a suspension of magnesium hydroxide ($Mg(OH)2$) taken for heartburn. Its reaction with stomach acid is…
Milk of magnesia is a suspension of magnesium hydroxide ($Mg(OH)_2$) taken for heartburn. Its reaction with stomach acid is $Mg(OH)_2 + 2\ HCl \rightarrow MgCl_2 + 2\ H_2O$.
- a) How many moles of $HCl$ does $1\ \text{mol}$ of $Mg(OH)_2$ neutralise?
- b) If the stomach has an excess of $0,1\ \text{mol}$ of $HCl$, how many moles of $Mg(OH)_2$ are needed to neutralise it?
In a laboratory flask, there are $0,2\ \text{mol}$ of sulphuric acid ($H_2SO_4$). a) Write the balanced equation for its neutralisation with sodium hydroxide ($NaOH$),…
In a laboratory flask, there are $0,2\ \text{mol}$ of sulphuric acid ($H_2SO_4$).
- a) Write the balanced equation for its neutralisation with sodium hydroxide ($NaOH$), which produces sodium sulphate ($Na_2SO_4$) and water.
- b) Calculate how many moles of $NaOH$ are needed to neutralise all the acid.
- c) If we were to add only $0,2\ \text{mol}$ of $NaOH$, would the solution be acidic, neutral or basic? Justify your answer using stoichiometry.
Back to the start: Acidic wastewater from a factory is neutralised by adding a base before it is discharged; likewise, lime is a base that neutralises the acidity of the soil, just as an antacid neutralises the excess hydrochloric acid in the stomach.