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ESO Y4A · Physics and Chemistry
Chemical change · Chemical equations

Stoichiometric calculations

An engineer designing a boiler needs to know, in grams, how much oxygen is required to burn the fuel and how much carbon dioxide will come out of the chimney. The balanced equation on its own does not give grams: it gives a ratio of molecules. The bridge between what you weigh on the balance and what the equation counts is the mole.

Before you start, make sure you know: Chemical equations and balancing them (3rd ESO)
Before you start, make sure you know: Atomic mass and molecular mass (2nd ESO)

The molar ratio: reading the coefficients directly

When measuring the volumes of gas in the formation of water, $2\ \text{L}$ of hydrogen react exactly with $1\ \text{L}$ of oxygen, but by mass they combine in a proportion of $2\ \text{g}$ of hydrogen for every $16\ \text{g}$ of oxygen. Why do chemical substances combine in simple ratios of particles and not of grams?

Combustion of methane with molecular models: one CH₄ molecule and two O₂ molecules produce one CO₂ and two H₂O; the same 1 : 2 : 1 : 2 ratio is read as moles. CH₄ + 2 O₂ → CO₂ + 2 H₂O + + CH₄ 2 O₂ CO₂ 2 H₂O 1 mol 2 mol 1 mol 2 mol carbon hydrogen oxygen

Balance this equation using the interactive and, once it is balanced, read its coefficients as moles: how many moles of hydrogen are needed for every mole of nitrogen?

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The balanced equation for the combustion of methane, $\text{CH}4 + 2\ \text{O}2 \rightarrow \text{CO}2 + 2\ \text{H}2\text{O}$, can also be read in moles. a) How many…

The balanced equation for the combustion of methane, $\text{CH}_4 + 2\ \text{O}_2 \rightarrow \text{CO}_2 + 2\ \text{H}_2\text{O}$, can also be read in moles.

  1. a) How many moles of oxygen are needed to burn $3\ \text{mol}$ of methane?
  2. b) How many moles of carbon dioxide and how many of water are formed then?
Solve
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The equation for the formation of water is $2\ \text{H}2 + \text{O}2 \rightarrow 2\ \text{H}2\text{O}$. If $4\ \text{mol}$ of hydrogen is completely burned: a) How many…

The equation for the formation of water is $2\ \text{H}_2 + \text{O}_2 \rightarrow 2\ \text{H}_2\text{O}$. If $4\ \text{mol}$ of hydrogen is completely burned:

  1. a) How many moles of oxygen are consumed?
  2. b) How many moles of water are formed?
Solve

Molar mass: from moles to grams

A dozen large eggs weighs about $750\ \text{g}$, whereas a dozen lentils barely reaches $0{,}5\ \text{g}$, even though both groups contain exactly twelve items. If a mole always contains the same fixed number of particles, why does a mole of water weigh $18\ \text{g}$ and a mole of glucose weigh $180\ \text{g}$?

Diagram of the conversion between mass in grams and amount of substance in moles by dividing or multiplying by the molar mass. mass (g) moles (mol) ÷ M × M
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The glucose used by your muscles when playing sport has the formula $\text{C}6\text{H}{12}\text{O}6$. Calculate its molar mass and explain in a sentence what this value…

The glucose used by your muscles when playing sport has the formula $\text{C}_6\text{H}_{12}\text{O}_6$. Calculate its molar mass and explain in a sentence what this value means (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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A glass contains $36\ \text{g}$ of water. Knowing that the molar mass of water is $18\ \text{g/mol}$, calculate how many moles of water are in the glass.

A glass contains $36\ \text{g}$ of water. Knowing that the molar mass of water is $18\ \text{g/mol}$, calculate how many moles of water are in the glass.

Solve
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A flask contains $0,5\ \text{mol}$ of carbon dioxide. Knowing that the molar mass of $\text{CO}2$ is $44\ \text{g/mol}$, calculate the mass of gas contained in the flask.

A flask contains $0,5\ \text{mol}$ of carbon dioxide. Knowing that the molar mass of $\text{CO}_2$ is $44\ \text{g/mol}$, calculate the mass of gas contained in the flask.

Solve

The complete route: mass → moles → moles → mass

Diagram of the stoichiometric route: the mass of the given substance is divided by the molar mass to obtain its moles, the molar ratio from the equation gives the moles asked for, and multiplying by the molar mass gives the mass asked for. mass given ÷M moles given molar ratio moles asked for ×M mass asked for
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In a barbecue, $12\ \text{g}$ of carbon burns according to the equation $\text{C} + \text{O}2 \rightarrow \text{CO}2$. Calculate, by converting through moles, what mass…

In a barbecue, $12\ \text{g}$ of carbon burns according to the equation $\text{C} + \text{O}_2 \rightarrow \text{CO}_2$. Calculate, by converting through moles, what mass of carbon dioxide is formed (atomic masses: $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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An amateur rocket burns $4\ \text{g}$ of hydrogen according to the equation $2\ \text{H}2 + \text{O}2 \rightarrow 2\ \text{H}2\text{O}$. Calculate, by converting through…

An amateur rocket burns $4\ \text{g}$ of hydrogen according to the equation $2\ \text{H}_2 + \text{O}_2 \rightarrow 2\ \text{H}_2\text{O}$. Calculate, by converting through moles, the mass of water vapour formed (molar masses: $\text{H}_2 = 2\ \text{g/mol}$; $\text{H}_2\text{O} = 18\ \text{g/mol}$).

Solve
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A home boiler burns $16\ \text{g}$ of methane according to the equation $\text{CH}4 + 2\ \text{O}2 \rightarrow \text{CO}2 + 2\ \text{H}2\text{O}$. Calculate, by…

A home boiler burns $16\ \text{g}$ of methane according to the equation $\text{CH}_4 + 2\ \text{O}_2 \rightarrow \text{CO}_2 + 2\ \text{H}_2\text{O}$. Calculate, by converting through moles:

  1. a) The mass of oxygen it consumes.
  2. b) The mass of carbon dioxide it emits.

(molar masses: $\text{CH}_4 = 16\ \text{g/mol}$; $\text{O}_2 = 32\ \text{g/mol}$; $\text{CO}_2 = 44\ \text{g/mol}$).

Solve

Calculations with industrial quantities

The method does not change even if the quantities are enormous: you just have to watch the units (kilograms, tonnes) before converting to moles.

Section of a blast furnace: 320 kg of Fe₂O₃ enter at the top, the ratio 112/160 is applied and molten iron leaves at the bottom, 224 kg of Fe. 320 kg Fe₂O₃ × 112/160 blast furnace reactor 224 kg Fe same ratio
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In a lime kiln, $100\ \text{g}$ of calcium carbonate decomposes according to the equation $\text{CaCO}3 \rightarrow \text{CaO} + \text{CO}2$. Calculate, by converting…

In a lime kiln, $100\ \text{g}$ of calcium carbonate decomposes according to the equation $\text{CaCO}_3 \rightarrow \text{CaO} + \text{CO}_2$. Calculate, by converting through moles, the mass of quicklime ($\text{CaO}$) obtained (molar masses: $\text{CaCO}_3 = 100\ \text{g/mol}$; $\text{CaO} = 56\ \text{g/mol}$).

Solve
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A steel part containing $56\ \text{g}$ of iron oxidises completely according to the equation $4\ \text{Fe} + 3\ \text{O}2 \rightarrow 2\ \text{Fe}2\text{O}3$. Calculate,…

A steel part containing $56\ \text{g}$ of iron oxidises completely according to the equation $4\ \text{Fe} + 3\ \text{O}_2 \rightarrow 2\ \text{Fe}_2\text{O}_3$. Calculate, by converting through moles, the mass of iron(III) oxide formed (molar masses: $\text{Fe} = 56\ \text{g/mol}$; $\text{Fe}_2\text{O}_3 = 160\ \text{g/mol}$).

Solve
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An electrolysis apparatus decomposes $90\ \text{g}$ of water according to the equation $2\ \text{H}2\text{O} \rightarrow 2\ \text{H}2 + \text{O}2$. Calculate, by…

An electrolysis apparatus decomposes $90\ \text{g}$ of water according to the equation $2\ \text{H}_2\text{O} \rightarrow 2\ \text{H}_2 + \text{O}_2$. Calculate, by converting through moles:

  1. a) The mass of hydrogen obtained.
  2. b) The mass of oxygen released.

(molar masses: $\text{H}_2\text{O} = 18\ \text{g/mol}$; $\text{H}_2 = 2\ \text{g/mol}$; $\text{O}_2 = 32\ \text{g/mol}$).

Solve

The limiting reactant: when one is left over

Five H₂ molecules and two O₂ molecules react: the O₂ runs out, four H₂O molecules are formed and one H₂ is left over; the smallest moles/coefficient quotient identifies the limiting reactant. Before After H₂: 5/2 = 2,5 O₂: 2/1 = 2 limiting: smallest quotient 4 H₂O H₂ in excess Each molecule drawn represents 1 mol
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In a container, $10\ \text{g}$ of hydrogen is mixed with $64\ \text{g}$ of oxygen and a spark is ignited: $2\ \text{H}2 + \text{O}2 \rightarrow 2\ \text{H}2\text{O}$.…

In a container, $10\ \text{g}$ of hydrogen is mixed with $64\ \text{g}$ of oxygen and a spark is ignited: $2\ \text{H}_2 + \text{O}_2 \rightarrow 2\ \text{H}_2\text{O}$. The diagram summarises the experiment data:

hydrogen (H₂) 10 g oxygen (O₂) 64 g water (H₂O) ? g excess reactant ? g
  1. a) Calculate the moles of each reactant and deduce which one is in excess.
  2. b) What mass of water is formed?
  3. c) What mass of excess reactant remains unreacted?

(molar masses: $\text{H}_2 = 2\ \text{g/mol}$; $\text{O}_2 = 32\ \text{g/mol}$; $\text{H}_2\text{O} = 18\ \text{g/mol}$).

Solve
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A reactor aims to produce $34\ \text{g}$ of ammonia according to the equation $\text{N}2 + 3\ \text{H}2 \rightarrow 2\ \text{NH}3$. Calculate, by converting through…

A reactor aims to produce $34\ \text{g}$ of ammonia according to the equation $\text{N}_2 + 3\ \text{H}_2 \rightarrow 2\ \text{NH}_3$. Calculate, by converting through moles, the minimum mass of hydrogen that must be fed in (molar masses: $\text{H}_2 = 2\ \text{g/mol}$; $\text{NH}_3 = 17\ \text{g/mol}$).

Solve

Back to the start: If the engineer burns $160\ \text{g}$ of methane ($\text{CH}_4$, $10\ \text{mol}$), they will need $20\ \text{mol}$ of $\text{O}_2$ ($640\ \text{g}$) and know that $10\ \text{mol}$ of $\text{CO}_2$, equivalent to $440\ \text{g}$, will be released through the chimney.

Summary

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