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Math 7 · Science
Matter · Elements and compounds

"Naming elements, ions and binary compounds"

The iron in a bridge and the carbon dioxide you breathe out are two substances with very different names, but those names are not chosen at random: they follow fixed rules, the same all over the world, so that any formula can be named without ambiguity.

Elements

Both iron nails and the gas inside an oxygen tank are made up of atoms of a single kind: how do we classify and name these materials, which cannot be broken down into other substances?

Comparison between separate iron atoms (Fe), grouped without forming molecules, and a diatomic oxygen molecule (O₂) with two atoms joined together, examples of elements. Iron Fe Fe Fe iron (Fe): separate atoms each atom is independent Oxygen O O oxygen (O₂): molecule two O atoms joined

Elements made of separate atoms are named with the name of the element: iron, helium. If they form molecules, a prefix shows how many atoms are in each molecule: $\text{O}_2$ is dioxygen (or, simply, oxygen) and $\text{O}_3$ is trioxygen (ozone).

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The iron in a bridge ($\text{Fe}$) and the carbon dioxide we release when breathing ($\text{CO}2$): one of the two is a simple substance and the other is a compound. The…

The iron in a bridge ($\text{Fe}$) and the carbon dioxide we release when breathing ($\text{CO}_2$): one of the two is a simple substance and the other is a compound. The figure shows their particle models.

Fe Fe Fe Fe Fe Fe iron (Fe) O C O O C O carbon dioxide (CO₂)

Which is which? Explain the difference between the two.

Solve
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Oxygen ($\text{O}2$), nitrogen ($\text{N}2$), iron ($\text{Fe}$) and helium ($\text{He}$) are simple substances. Look at their formulas and state which of them form…

Oxygen ($\text{O}_2$), nitrogen ($\text{N}_2$), iron ($\text{Fe}$) and helium ($\text{He}$) are simple substances. Look at their formulas and state which of them form molecules, which are made up of individual atoms and whether any of them fits neither case.

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Monatomic ions

An ion is an atom that has gained or lost electrons, so it has an electric charge. If it loses electrons it has more protons than electrons and is positive; if it gains electrons it is negative. Each ion has its own name.

A neutral sodium atom (Na) loses an electron and becomes the sodium ion Na⁺, with a charge of +1. 11p⁺ Na neutral atom e− loses 1 e− 11p⁺ Na⁺ sodium ion, charge +1
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When a sodium atom loses an electron, it becomes $\text{Na}^+$. The figure shows the process. a) Explain what an ion is. b) Does $\text{Na}^+$ have a positive or a…

When a sodium atom loses an electron, it becomes $\text{Na}^+$. The figure shows the process.

A sodium atom with 11 electrons loses one electron from its outer shell and is left with 10 electrons Na sodium atom loses 1 electron Na⁺ e−
  1. a) Explain what an ion is.
  2. b) Does $\text{Na}^+$ have a positive or a negative charge?
  3. c) What is this ion called?
Solve
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Name these three monatomic ions: $\text{Cl}^-$, $\text{Ca}^{2+}$ and $\text{O}^{2-}$. Hint: positive ions keep the name of the atom (for example, the $\text{Na}^+$ ion…

Name these three monatomic ions: $\text{Cl}^-$, $\text{Ca}^{2+}$ and $\text{O}^{2-}$. Hint: positive ions keep the name of the atom (for example, the $\text{Na}^+$ ion is called sodium ion) and negative ions end in -ide (for example, the $\text{S}^{2-}$ ion is called sulfide ion).

Solve
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In your bones, calcium is present as $\text{Ca}^{2+}$. a) What does that $2+$ mean? b) How many electrons has the calcium atom lost? c) What is this ion called?

In your bones, calcium is present as $\text{Ca}^{2+}$.

  1. a) What does that $2+$ mean?
  2. b) How many electrons has the calcium atom lost?
  3. c) What is this ion called?
Solve

Naming binary compounds with prefixes

A binary compound is made up of two elements. When both elements are nonmetals, the compound is molecular and its name uses Greek prefixes that show how many atoms there are of each one.

Ball-and-stick models of the molecules of carbon monoxide (one carbon atom joined to one oxygen atom by a triple bond) and carbon dioxide (one carbon between two oxygens, with two double bonds, in a straight line). C O CO carbon monoxide O C O CO₂ carbon dioxide
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Many fire extinguishers are filled with $\text{CO}2$ gas. Naming it with Greek prefixes (mono-, di-, tri-) according to the number of oxygen atoms it has, what is the…

Many fire extinguishers are filled with $\text{CO}_2$ gas. Naming it with Greek prefixes (mono-, di-, tri-) according to the number of oxygen atoms it has, what is the name of this gas?

Solve
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Using the prefixes mono-, di-, and tri-, write the formula for these two substances: carbon monoxide and carbon dioxide. What is the difference between the two molecules?

Using the prefixes mono-, di-, and tri-, write the formula for these two substances: carbon monoxide and carbon dioxide. What is the difference between the two molecules?

Solve

Naming ionic compounds (metal + nonmetal)

Table salt, $\text{NaCl}$, contains a metal and a nonmetal. Do we need prefixes to name it?

A compound of a metal with a nonmetal is made of ions. Name the metal first (it keeps its name), then the nonmetal with the ending -ide. You do not say the subscripts.

A sodium ion Na⁺ next to a chloride ion Cl⁻: the compound NaCl is named sodium chloride. Na⁺ Cl⁻ sodium chloride, NaCl
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When a metal combines with a non-metal, the compound is named by placing the name of the metal first and then the name of the non-metal with the ending -ide. Apply the…

When a metal combines with a non-metal, the compound is named by placing the name of the metal first and then the name of the non-metal with the ending -ide. Apply the rule and name table salt, $\text{NaCl}$, as well as the compound $\text{CaS}$.

Solve
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Compounds of oxygen with another element are called oxides and are named "[element] oxide". Milk of magnesia from drugstores contains $\text{MgO}$: name it. Also name…

Compounds of oxygen with another element are called oxides and are named "[element] oxide". Milk of magnesia from drugstores contains $\text{MgO}$: name it. Also name the compound $\text{Na}_2\text{O}$.

Solve
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When hydrogen combines with a metal, the compound is called a hydride. Name these two compounds: $\text{NaH}$ and $\text{CaH}2$.

When hydrogen combines with a metal, the compound is called a hydride. Name these two compounds: $\text{NaH}$ and $\text{CaH}_2$.

Solve

Metals with more than one charge: Stock system

Some metals, such as iron, can form more than one different ion ($\text{Fe}^{2+}$ or $\text{Fe}^{3+}$). In those cases we need to say which charge the metal has in that compound.

Two iron oxides: FeO, with one Fe²⁺ ion for each oxide ion O²⁻, and Fe₂O₃, with two Fe³⁺ ions and three oxide ions; the charge of iron, 2+ or 3+, is written in Roman numerals: (II) and (III). FeO Fe₂O₃ O²⁻ Fe²⁺ O²⁻ Fe³⁺ O²⁻ Fe³⁺ O²⁻ iron(II) oxide iron(III) oxide charge 2+ → (II) charge 3+ → (III)
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Classify each substance as an element, oxide, hydride, or binary salt, and write its name: a) $\text{O}2$ b) $\text{Na}2\text{O}$ c) $\text{CaH}2$ d) $\text{FeS}$ e)…

Classify each substance as an element, oxide, hydride, or binary salt, and write its name:

  1. a) $\text{O}_2$
  2. b) $\text{Na}_2\text{O}$
  3. c) $\text{CaH}_2$
  4. d) $\text{FeS}$
  5. e) $\text{N}_2$
  6. f) $\text{MgO}$
Solve

From formula to name and back

Common salt ($\text{NaCl}$) is made of positive and negative ions, but a salt shaker does not give you an electric shock when you touch it: how do those ions combine so that the final compound has no net charge?

To write the formula of a compound from its ions, the positive and negative charges must balance so that they add up to zero.

Balancing of electric charges between two Al³⁺ ions and three O²⁻ ions to obtain the neutral formula Al₂O₃. Al³⁺ Al³⁺ O²⁻ O²⁻ O²⁻ +6 (2×3) and −6 (3×2) cancel out: Al₂O₃
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Fluorite, a colorful mineral, is $\text{CaF}2$. a) Name this compound (remember the ending -ide). b) Now in reverse: write the formula of sodium sulfide, which has two…

Fluorite, a colorful mineral, is $\text{CaF}_2$.

  1. a) Name this compound (remember the ending -ide).
  2. b) Now in reverse: write the formula of sodium sulfide, which has two sodium atoms for every sulfur atom.
Solve
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Common salt is made up of $\text{Na}^+$ ions and $\text{Cl}^-$ ions arranged in a lattice. The figure shows a section of that lattice. a) Explain why the same number of…

Common salt is made up of $\text{Na}^+$ ions and $\text{Cl}^-$ ions arranged in a lattice. The figure shows a section of that lattice.

Na Na Na Na Na Na Na Na Cl Cl Cl Cl Cl Cl Cl Cl Na+ Cl−
  1. a) Explain why the same number of ions of each type is needed for the salt to be neutral.
  2. b) Write the formula of the salt and reason why it cannot be $\text{Na}_2\text{Cl}$.
Solve

Back to the start: the iron in a bridge ($\text{Fe}$) is an element named just "iron", and the carbon dioxide you breathe out ($\text{CO}_2$) is a molecular compound of two nonmetals, so its name uses a prefix.

Summary

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