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Matter · The structure of matter

Atomic models (from Dalton to Bohr)

Imagine you keep cutting a piece of iron in half, again and again, like slicing a pizza slice into smaller and smaller bites. Would you eventually reach a piece so small that it could not be cut any further? That question is more than two thousand years old. The answer we give today did not occur to anyone all at once: it was built up gradually, through four different models of the atom, each one better than the last, and scientists still refine it today.

Dalton: the atom as a solid ball

When $1.0\text{ g}$ of hydrogen reacts with $8.0\text{ g}$ of oxygen, exactly $9.0\text{ g}$ of water is always produced, and if you add more oxygen it does not react partially, the extra simply remains: why do chemical elements always combine in fixed, exact proportions by mass?

In 1805, John Dalton proposed that all matter is made of atoms: tiny, solid, indivisible little balls.

Dalton's model: one solid spherical atom of one element next to three smaller atoms of a different element, all identical to one another. Element A Dalton's atom: a solid ball Element B atoms identical to one another

With this very simple idea, Dalton could already explain why elements are different from one another and why they always combine in the same proportions to form compounds.

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In Physics class, the teacher shows a billiard ball and says that this is how Dalton imagined atoms around the year $1805$, as shown in the figure. Explain in your own…

In Physics class, the teacher shows a billiard ball and says that this is how Dalton imagined atoms around the year $1805$, as shown in the figure.

atom

Explain in your own words what an atom is according to Dalton's model and what two properties that "ball" had.

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In an assignment, Mateo writes: "Dalton's model was wrong, so it was completely useless." You disagree. Explain two things that Dalton's model did explain well (why…

In an assignment, Mateo writes: "Dalton's model was wrong, so it was completely useless." You disagree. Explain two things that Dalton's model did explain well (why different elements exist and how their atoms combine) and one thing it could not explain, which forced it to be changed.

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Thomson: the plum pudding

When you rub a plastic pen with a wool sweater and find that it attracts little pieces of paper, or you get a static shock from a doorknob after walking across a carpet, matter is showing electrical properties: if atoms were solid, neutral spheres as Dalton said, where does that electric charge come from?

In 1897, J. J. Thomson was carrying out experiments with cathode ray tubes and discovered a tiny, negatively charged particle coming from inside the atom: the electron. This meant something enormous: Dalton's atom, which was supposed to be indivisible, actually had smaller pieces inside it.

Since the whole atom is neutral, Thomson imagined that the electrons (negative charge) were embedded in a mass of positive charge, like plums in a pudding.

Thomson's model: a sphere of positive charge (the pudding) with negative electrons embedded like plums, so that the atom is neutral. + + + + + + + + + + + + − − − − − electron (−) positive mass (+) positive mass (the "pudding") + electrons (the "plums") total charge: neutral
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Liam's grandmother makes a plum pudding, like the one in the figure. Thomson imagined the atom as this dessert: explain what the pudding mass represents in his model and…

Liam's grandmother makes a plum pudding, like the one in the figure.

pudding mass raisins

Thomson imagined the atom as this dessert: explain what the pudding mass represents in his model and what the raisins represent.

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In a science museum, Leo observes a cathode ray tube like the one Thomson used in his experiments, similar to the one in the figure. Which particle did Thomson discover…

In a science museum, Leo observes a cathode ray tube like the one Thomson used in his experiments, similar to the one in the figure.

cathode (−) anode (+) ray screen

Which particle did Thomson discover using this apparatus and what electrical charge does it have?

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Old cathode ray tube TVs worked using cathode rays, the same ones Thomson used to discover the electron in $1897$. The electron is a particle that comes from inside the…

Old cathode ray tube TVs worked using cathode rays, the same ones Thomson used to discover the electron in $1897$. The electron is a particle that comes from inside the atom: explain why this discovery forced a change to Dalton's model.

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To explain the models, a group of students uses a watermelon with seeds as an image of Thomson's model. a) Explain what each part of the watermelon represents in that…

To explain the models, a group of students uses a watermelon with seeds as an image of Thomson's model.

  1. a) Explain what each part of the watermelon represents in that model.
  2. b) Propose an everyday object or situation of your own that represents Rutherford's model and explain what each element is.
  3. c) No comparison is perfect: point out a flaw in using a watermelon as a model of the atom.
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Rutherford: the almost empty atom

In 1911, Ernest Rutherford fired $\alpha$ particles (with positive charge) at a very thin gold foil, in order to "feel" the inside of Thomson's atom. Think of throwing baseballs at a curtain: if they almost all pass through but a few bounce straight back, something hard is hidden in there.

Animation of Rutherford's experiment: alpha particles pass in a straight line through a gold foil; one is deflected as it passes close to the nucleus and another bounces back after hitting it. gold foil (the red dot is the nucleus)

If the atom were a plum pudding, with the positive charge spread throughout its volume, no particle should bounce back. The fact that some did can only be explained if all the positive charge is concentrated in a tiny, very heavy point.

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Emma watches Rutherford's gold foil experiment in a documentary: positively charged $\alpha$ particles were fired at an extremely thin sheet of gold foil, as shown in…

Emma watches Rutherford's gold foil experiment in a documentary: positively charged $\alpha$ particles were fired at an extremely thin sheet of gold foil, as shown in the figure.

α source α particles gold foil ? screen

What happened to the vast majority of the particles when they reached the foil? What conclusion did Rutherford draw about the inside of the atom?

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In the gold foil experiment, three things were observed: most $\alpha$ particles passed through the foil without being deflected, a few were deflected, and very rarely,…

In the gold foil experiment, three things were observed: most $\alpha$ particles passed through the foil without being deflected, a few were deflected, and very rarely, one bounced back, as shown in the figure.

α α particles gold foil

Write down the conclusion Rutherford drew from each of the three observations.

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In a class debate, Nora argues that the gold foil experiment disproved Thomson's model. If the atom were truly a sphere of positive charge with embedded electrons, what…

In a class debate, Nora argues that the gold foil experiment disproved Thomson's model. If the atom were truly a sphere of positive charge with embedded electrons, what should have happened to the $\alpha$ particles upon reaching the foil? Which observation from the experiment does not fit this prediction? Justify your answer.

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Rutherford's model is called the "planetary model" because it resembles the Solar System, as shown in the figure. State one similarity and one difference between the…

Rutherford's model is called the "planetary model" because it resembles the Solar System, as shown in the figure.

+ nucleus (+) e−

State one similarity and one difference between the planets orbiting the Sun and the electrons orbiting the nucleus (think about which force holds each system together).

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When Rutherford proposed his model, he could not ignore what was already known: for example, that atoms are electrically neutral. Explain how atomic neutrality fits into…

When Rutherford proposed his model, he could not ignore what was already known: for example, that atoms are electrically neutral. Explain how atomic neutrality fits into Rutherford's model (positive nucleus and electrons) and why a new model must also explain the facts that the previous model already explained well.

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Imagine that in the gold foil experiment, most of the $\alpha$ particles had bounced back instead of passing through the foil. What would Rutherford have concluded about…

Imagine that in the gold foil experiment, most of the $\alpha$ particles had bounced back instead of passing through the foil. What would Rutherford have concluded about the inside of the atom in that case? Which known model would that conclusion most closely resemble? Explain your reasoning.

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In the gold foil experiment, for every $8000$ $\alpha$ particles fired, about $7992$ passed through the foil without being deflected, about $7$ were deflected, and only…

In the gold foil experiment, for every $8000$ $\alpha$ particles fired, about $7992$ passed through the foil without being deflected, about $7$ were deflected, and only $1$ bounced back.

  1. a) Calculate what percentage of the particles passed through the foil cleanly.
  2. b) What fraction of the fired particles bounced back?
  3. c) Using these numbers, explain why Rutherford stated that the atom is mostly empty space and that the nucleus is tiny.
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$\alpha$ particles have a positive charge, just like the nucleus of the atom, as shown in the figure. a) Using the forces between electric charges, explain why a…

$\alpha$ particles have a positive charge, just like the nucleus of the atom, as shown in the figure.

+ nucleus α (+) is deflected α (+) bounces back
  1. a) Using the forces between electric charges, explain why a $\alpha$ particle passing near the nucleus is deflected from its path.
  2. b) Why are the particles that bounce back precisely those that get closest to the nucleus?
  3. c) If the foil were bombarded with uncharged particles, would you expect to see the same deflections? Justify your answer.
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Some scientists repeat the experiment with a foil made of a metal other than gold and observe that twice as many $\alpha$ particles now bounce back, although they are…

Some scientists repeat the experiment with a foil made of a metal other than gold and observe that twice as many $\alpha$ particles now bounce back, although they are still very few.

  1. a) Is the idea that the atom is mostly empty space still valid? Why?
  2. b) Propose a hypothesis explaining why more particles bounce back with this metal (think about what its nucleus might be like compared to gold).
  3. c) What new experiment would you carry out to test your hypothesis? Explain your reasoning.
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Bohr: electrons in allowed orbits

Rutherford's model had a serious problem: according to the laws of physics known at the time, an orbiting electron should gradually lose energy and end up falling into the nucleus. If that happened, no atom would be stable, and yet atoms are stable.

In 1913, Niels Bohr proposed a new rule: electrons cannot orbit at just any distance from the nucleus; they can only occupy certain allowed orbits, like the rungs of a ladder. As long as an electron is on one of those "rungs", it does not lose energy and does not fall.

Move the sliders in the interactive and notice how the shells fill up, one by one, as you add electrons.

Bohr's model is not the last word. Today scientists use the electron cloud model: electrons are not on fixed paths, but we can describe the regions where they are most likely to be found.

Why models change

The four models are not four unrelated ideas: each one arises from an experiment that the previous model could not explain. A scientific model is a tool, like a video game that gets updated to fix bugs. When new evidence does not fit, scientists revise the model. An explanation backed by lots of evidence is a theory; a hypothesis is a testable idea; a law describes a pattern.

Here are examples from this page. A hypothesis is a testable idea, like Thomson's idea that the atom is a positive pudding with embedded electrons. A theory is a well-tested explanation, like atomic theory, which says all matter is made of atoms. A law describes a pattern in nature, like the law of conservation of mass: the mass of the reactants equals the mass of the products. The gold foil experiment was the evidence that did not fit the pudding hypothesis, so scientists revised the model.

The four atomic models in order: Dalton (sphere with no parts), Thomson (positive sphere with embedded electrons), Rutherford (small nucleus with electrons around it) and Bohr (electrons in orbits); each arrow is an experiment that the previous model could not explain. Dalton Thomson Rutherford Bohr electron (charge −) positive charge (+) each arrow is an experiment that did not fit the previous model
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Some collectible cards of "atomic scientists" show these dates: Thomson, $1897$; Bohr, $1913$; Dalton, $1805$; Rutherford, $1911$. Order the four atomic models from…

Some collectible cards of "atomic scientists" show these dates: Thomson, $1897$; Bohr, $1913$; Dalton, $1805$; Rutherford, $1911$. Order the four atomic models from oldest to most recent.

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Mario's favorite game is updated frequently to fix bugs and add improvements. Something similar happens with scientific models: explain why scientists replace one model…

Mario's favorite game is updated frequently to fix bugs and add improvements. Something similar happens with scientific models: explain why scientists replace one model with a new one.

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These four descriptions of atomic models are out of order: a) "Electrons orbit a central nucleus, like planets around the Sun." b) "The atom is a solid, indivisible…

These four descriptions of atomic models are out of order:

  1. a) "Electrons orbit a central nucleus, like planets around the Sun."
  2. b) "The atom is a solid, indivisible ball."
  3. c) "Electrons can only be in certain permitted orbits."
  4. d) "The atom is a positive sphere with embedded electrons."

Order them chronologically, from the oldest model to the most recent, and write the name of the scientist who proposed each one.

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In the exhibit "The Detectives of the Atom" there are four misplaced panels. Match each description with its scientist: Dalton, Thomson, Rutherford, or Bohr. a) "The…

In the exhibit "The Detectives of the Atom" there are four misplaced panels. Match each description with its scientist: Dalton, Thomson, Rutherford, or Bohr.

  1. a) "The atom is a solid, indivisible sphere."
  2. b) "Electrons are embedded in a positively charged sphere, like raisins in a pudding."
  3. c) "Almost the entire atom is empty space and positive charge is concentrated in a very small nucleus."
  4. d) "Electrons can only occupy certain permitted orbits."
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Write a short encyclopedia entry titled "The history of the atom in four models". For each scientist (Dalton, Thomson, Rutherford, and Bohr), state what their model…

Write a short encyclopedia entry titled "The history of the atom in four models". For each scientist (Dalton, Thomson, Rutherford, and Bohr), state what their model contributed and what observation or experiment supported it.

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Your eight-year-old cousin asks you why the diagrams of the atom in science books change. Write a simple explanation for them (you can compare it to updating a map when…

Your eight-year-old cousin asks you why the diagrams of the atom in science books change. Write a simple explanation for them (you can compare it to updating a map when a new path is discovered), explaining how science moved from Dalton's model to Bohr's model and what role experiments played in these changes.

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Back to the beginning: Yes, you would reach a limit: the iron atom is the smallest portion that is still iron; if you try to break it up further, it stops being iron and you get loose subatomic particles (protons, neutrons and electrons).

Summary

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