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Factors that affect reactions and dissolving

A banana ripens in days on the kitchen counter, but takes much longer in the refrigerator. Vinegar and baking soda fizz instantly, but the iron of a railing takes years to rust. These are all chemical reactions, yet they proceed at very different rates. What makes a reaction fast or slow?

The reaction as a collision of particles

Two reactants can be kept in neighboring bottles for years without changing, but as soon as they are mixed in the same flask, new substances appear: what exactly has to happen on the microscopic scale for a reaction to start?

Collision theory: at the top, an effective collision between A₂ and B₂ molecules with the right energy and orientation, which breaks bonds and forms two AB molecules; at the bottom, a non-effective collision with the wrong orientation, in which the molecules bounce off without reacting. before during the collision after Effective collision: right energy and orientation reactants: A₂ and B₂ bonds are broken and others are formed products: 2 AB Non-effective collision: the particles bounce off reactants: A₂ and B₂ wrong orientation they bounce off without reacting atom A atom B
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A banana ripening on the kitchen table happens much faster than inside the refrigerator. What factor is accelerating ripening in one case and slowing it down in the…

A banana ripening on the kitchen table happens much faster than inside the refrigerator. What factor is accelerating ripening in one case and slowing it down in the other? Briefly explain how this factor acts.

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The fish we buy is kept in the freezer so that it takes much longer to spoil. What factor are we controlling by freezing it, and why does it slow down decomposition…

The fish we buy is kept in the freezer so that it takes much longer to spoil. What factor are we controlling by freezing it, and why does it slow down decomposition reactions?

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Temperature

A glow stick gives off an intense light in a glass of hot water but almost goes dark when it is put into ice water: why does temperature change the rate of a chemical reaction so much? Remember: temperature measures the average kinetic energy of the particles.

Animation of two boxes with particles bouncing off the walls: in the cold one they move slowly and in the hot one four times faster, with many more bounces and little agitation lines accompanying each particle. cold hot: more agitated
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An effervescent vitamin C tablet takes $80\ \text{s}$ to dissolve completely in a glass of water at $10\ \celsius$ and only $20\ \text{s}$ in water at $30\ \celsius$.…

An effervescent vitamin C tablet takes $80\ \text{s}$ to dissolve completely in a glass of water at $10\ \celsius$ and only $20\ \text{s}$ in water at $30\ \celsius$. The graph summarizes the data:

20 40 60 80 0 80 s 20 s 10 °C 30 °C T (°C) t (s)
  1. a) How many times faster is the reaction at $30\ \celsius$ than at $10\ \celsius$?
  2. b) Explain this result considering how particles move as temperature increases.
Solve
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Almost all chemical reactions go faster when the temperature rises. The figure represents the particles of a gas at two different temperatures: Explain it using the…

Almost all chemical reactions go faster when the temperature rises. The figure represents the particles of a gas at two different temperatures:

10 °C 40 °C

Explain it using the particle model: what happens to the reactant particles and what consequence does this have for their collisions?

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Aitana mixes two colorless solutions in the lab and measures the time it takes for a yellow solid (a precipitate) to appear. She repeats the mixture at different…

Aitana mixes two colorless solutions in the lab and measures the time it takes for a yellow solid (a precipitate) to appear. She repeats the mixture at different temperatures and obtains: $80\ \text{s}$ at $10\ \celsius$, $40\ \text{s}$ at $20\ \celsius$ and $20\ \text{s}$ at $30\ \celsius$. The data are shown on the graph:

20 40 60 80 0 10 20 30 40 80 s 40 s 20 s ? T (°C) t (s)
  1. a) Describe in your own words the trend shown by the data.
  2. b) Looking at the trend, how much time would roughly be expected at $40\ \celsius$?
  3. c) Justify the trend using the particle model.
Solve

Concentration and the amount of oxygen available

Two containers of the same size: in air there are few oxygen molecules (O₂) and in pure oxygen there are many more in the same space. Air (21 % O₂) Pure oxygen (100 % O₂) little O₂ per volume more O₂ per volume

Surface area

A thick log takes hours to burn completely in the fireplace, but the same weight of wood as sawdust or shavings burns in seconds: how does the size of the pieces matter if the mass of reactant is the same? The same idea explains why sugar dissolves faster in water when it is ground finely: dissolving a solid in water (an aqueous solution, with water as the solvent and sugar as the solute) only happens where particles touch the water.

Comparison of surface area in contact with water: a whole sugar cube, with few faces exposed, versus the same volume divided into nine small grains, with many more faces exposed. Cube a single piece Granulated little surface in contact much more surface in contact =
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Olivia adds a sugar cube to her coffee with milk and Marco adds the same amount of granulated sugar to his, as shown in the figure. Both stir equally. Which of the two…

Olivia adds a sugar cube to her coffee with milk and Marco adds the same amount of granulated sugar to his, as shown in the figure. Both stir equally.

sugar cube granulated sugar

Which of the two will dissolve first? What factor affecting the rate of reaction explains the difference?

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To make an antacid take effect sooner, pharmacies sell it in effervescent tablets that dissolve in water, or it is recommended to crush the tablet. What factor is being…

To make an antacid take effect sooner, pharmacies sell it in effervescent tablets that dissolve in water, or it is recommended to crush the tablet. What factor is being exploited in both cases?

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In soup broth, fine salt dissolves almost instantly, while coarse salt takes much longer, even if the amount is the same. Explain the difference using the particle…

In soup broth, fine salt dissolves almost instantly, while coarse salt takes much longer, even if the amount is the same. Explain the difference using the particle model: consider which salt particles are in contact with water in each case.

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An oak log can burn for hours in a fireplace, but sawdust from the same oak, if scattered, burns almost instantly. a) What factor explains this difference? b) Explain…

An oak log can burn for hours in a fireplace, but sawdust from the same oak, if scattered, burns almost instantly.

  1. a) What factor explains this difference?
  2. b) Explain why smoking is banned in carpenter shops and why accumulated sawdust is cleared away frequently.
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Explosions have occurred in grain silos and old flour mills without any visible flame: a small spark in air laden with flour dust was enough. a) Explain why suspended…

Explosions have occurred in grain silos and old flour mills without any visible flame: a small spark in air laden with flour dust was enough.

  1. a) Explain why suspended flour dust burns much faster than the same flour piled in a sack.
  2. b) Which of the factors that speed up reactions is acting to an extreme degree?
  3. c) Propose a safety measure for these places and justify it.
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Catalysts

Diagram of a catalyst: the reactants pass through the catalyst, which is not used up, and turn into product faster; the catalyst is left intact and is reused. reactants catalyst without being used up product stays intact

Dissolving a solid in water

Why does hot cocoa powder disappear faster than cold? Concentration of a solution means the amount of solute per volume of solvent: more solute in the same water means a more concentrated solution. In an aqueous solution, water is the solvent and the substance that dissolves is the solute. A solid dissolves only where its particles touch water particles.

Designing an experiment to study a factor

Controlled experiment: two glasses with the same amount of milk and cocoa, each with a thermometer; glass 1 is at room temperature and glass 2 is hot and steaming, so the only difference is the temperature. glass 1: cold (room temperature) glass 2: hot cocoa milk thermometer thermometer same cocoa, same milk same cocoa, same milk only difference: the temperature
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Steel wool used for scrubbing burns with sparks when brought near a flame, whereas a nail made of the same material only rusts slowly over the years. a) What factor…

Steel wool used for scrubbing burns with sparks when brought near a flame, whereas a nail made of the same material only rusts slowly over the years.

  1. a) What factor explains why the same material reacts so differently?
  2. b) What is the slow oxidation undergone by the nail called?
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Ethan wants to check that temperature affects the rate at which cocoa powder dissolves in milk. Design the experiment for him: what materials he needs, which variable…

Ethan wants to check that temperature affects the rate at which cocoa powder dissolves in milk. Design the experiment for him: what materials he needs, which variable will change between the two glasses, what things he must keep exactly the same, and what he will measure to compare.

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You want to test the effect of surface area using two identical effervescent tablets: one whole and the other crushed into powder. a) Describe the procedure step by…

You want to test the effect of surface area using two identical effervescent tablets: one whole and the other crushed into powder.

  1. a) Describe the procedure step by step.
  2. b) Predict the result and justify it using the particle model.
  3. c) Explain why you must use the same amount of water at the same temperature in both glasses: what would happen to your conclusions if you did not?
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You prepare four glasses of water with sugar: glass 1 with cold water and a sugar cube, glass 2 with cold water and the same amount of granulated sugar, glass 3 with hot…

You prepare four glasses of water with sugar: glass 1 with cold water and a sugar cube, glass 2 with cold water and the same amount of granulated sugar, glass 3 with hot water and a sugar cube, and glass 4 with hot water and granulated sugar. The figure shows the four glasses:

Glass 1 cold water sugar cube Glass 2 cold water granulated Glass 3 hot water sugar cube Glass 4 hot water granulated
  1. a) Which two glasses would you compare to study only the effect of temperature? Justify your choice.
  2. b) And which two glasses would you compare to study only the effect of surface area?
  3. c) Which glass will take the least time to dissolve the sugar? Give reasons for your answer by combining both factors.
Solve

Communicating and evaluating an investigation

When comparing the rate of a reaction, record the variable you change, the ones you keep constant and the criterion for finishing. Use the same equipment and a supervised procedure: safety goggles and a lab apron, small quantities, open containers when a gas is produced and waste disposal as your teacher indicates. A fair test has one control (the setup without the change) and one changed variable.

Enter each repeat in a spreadsheet, calculate the average (mean) and plot temperature against mean time. Keep the original data and report their spread. In a team, take turns measuring, recording and checking; do not conclude that every reaction changes in exactly the same way. Compare the explanation with two sources, citing author and date, and separate observation from interpretation. Do not post classmates' names, images or data without permission.

The diagram shows how the main ideas are related:

Diagram of an investigation into the rate of a reaction: hypothesis with cold and warm water, three repeats of times for each temperature and a graph of temperature against mean time, with the points of the repeats showing their spread. Hypothesis ? cold warm Data and repeats 50 52 48 31 29 30 time (s) Conclusion and limitations mean t 50 s 30 s cold warm temperature

Back to the start: The banana keeps longer in the refrigerator because at a low temperature the particles move more slowly and the ripening reaction slows down; by contrast, vinegar and baking soda react instantly because their particles collide straight away throughout the liquid, whereas the rusting of the iron railing is very slow because it only happens on the surface exposed to the air.

Summary

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