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Math 7 · Science
Matter · Elements and compounds

Atomic mass and molecular mass

An atom weighs far less than you can imagine: you would need to put billions and billions of them together before a balance could notice anything. That is why, in chemistry, atoms are not weighed in grams, but with a unit made to their size.

Atomic mass: how much does an atom weigh?

If you try to weigh a speck of dust on a kitchen scale, it reads zero because it is far too light, but if you compare two tiny objects with each other you can tell which one weighs twice as much: how do we assign a mass to atoms if there is no balance capable of weighing them one at a time? Scientists compare each atom with a reference atom.

Comparison of atomic masses: a hydrogen atom of 1 u next to an oxygen atom of 16 u, which weighs 16 times more. H Hydrogen 1 u O Oxygen 16 u ×16 Oxygen weighs 16 times more than hydrogen

Historically, hydrogen, the lightest atom, was used as the reference, and it weighs about $1\ \text{u}$. Today, $1\ \text{u}$ is defined as $1/12$ the mass of a carbon-12 atom. Carbon weighs $12\ \text{u}$, that is, $12$ times more; oxygen weighs $16\ \text{u}$, $16$ times more. In the periodic table many atomic masses are decimals (chlorine is $35.5\ \text{u}$) because they are averages.

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What is the atomic mass of an element and in which unit is it measured? Look up the atomic mass of carbon and oxygen in the periodic table, and state which of the two…

What is the atomic mass of an element and in which unit is it measured? Look up the atomic mass of carbon and oxygen in the periodic table, and state which of the two atoms has more mass.

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These are the atomic masses of four elements: $\text{H} = 1\ \text{u}$, $\text{C} = 12\ \text{u}$, $\text{N} = 14\ \text{u}$ and $\text{O} = 16\ \text{u}$. a) How many…

These are the atomic masses of four elements: $\text{H} = 1\ \text{u}$, $\text{C} = 12\ \text{u}$, $\text{N} = 14\ \text{u}$ and $\text{O} = 16\ \text{u}$.

  1. a) How many times heavier is a carbon atom than a hydrogen atom?
  2. b) And a nitrogen atom than a hydrogen atom?
Solve
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Explain in your own words the difference between atomic mass and molecular mass, and give an example of each.

Explain in your own words the difference between atomic mass and molecular mass, and give an example of each.

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Molecular mass: adding up atoms

If you join three building pieces together to make a block, the whole block weighs exactly the same as its three pieces added up separately: does the same happen when several atoms bond to form a molecule?

Water molecule H₂O: one oxygen atom of 16 u bonded to two hydrogen atoms of 1 u each; the molecular mass is the sum, 18 u. H H O 2 H atoms 1 u (each) 1 u 1 O atom: 16 u M = 1 + 1 + 16 = 18 u
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The oxygen we breathe travels through the air forming molecules of $\text{O}2$. If the atomic mass of oxygen is $16\ \text{u}$, calculate the molecular mass of…

The oxygen we breathe travels through the air forming molecules of $\text{O}_2$. If the atomic mass of oxygen is $16\ \text{u}$, calculate the molecular mass of $\text{O}_2$.

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The figure shows the model of a water molecule. Calculate the molecular mass of water, $\text{H}2\text{O}$ (atomic masses: $\text{H} = 1\ \text{u}$;…

The figure shows the model of a water molecule.

O H H 16 u 1 u 1 u molecular mass = ?

Calculate the molecular mass of water, $\text{H}_2\text{O}$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{O} = 16\ \text{u}$).

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The gas that forms bubbles in soft drinks is carbon dioxide, $\text{CO}2$. The figure shows its molecule. Calculate its molecular mass (atomic masses:…

The gas that forms bubbles in soft drinks is carbon dioxide, $\text{CO}_2$. The figure shows its molecule.

O C O 16 u 12 u 16 u molecular mass = ?

Calculate its molecular mass (atomic masses: $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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The molecular mass of $\text{CO}2$ is $44\ \text{u}$ and the atomic mass of oxygen is $16\ \text{u}$. Look at the model in the figure. Without looking at the periodic…

The molecular mass of $\text{CO}_2$ is $44\ \text{u}$ and the atomic mass of oxygen is $16\ \text{u}$. Look at the model in the figure.

total molecular mass = 44 u O C O 16 u C = ? 16 u

Without looking at the periodic table, deduce the atomic mass of carbon and explain how you worked it out.

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A salt formed by a metal and chlorine has the formula $\text{XCl}2$ and a molecular mass of $111\ \text{u}$. The figure shows its model. a) Knowing that…

A salt formed by a metal and chlorine has the formula $\text{XCl}_2$ and a molecular mass of $111\ \text{u}$. The figure shows its model.

X X = ? Cl 35.5 u Cl 35.5 u total molecular mass = 111 u
  1. a) Knowing that $\text{Cl} = 35.5\ \text{u}$, calculate the atomic mass of element $\text{X}$.
  2. b) Look it up in the periodic table and identify the element.
  3. c) Write the full name of the salt.
Solve

Calculating with subscripts and parentheses

Before adding masses, count the atoms of each element. An element's subscript tells you how many atoms of that element there are. When there are parentheses with a subscript outside, that number multiplies everything inside.

Formula of calcium hydroxide, with an arrow showing that the outer subscript multiplies all the elements inside the parentheses. Ca(OH) 2 the 2 multiplies O and H: 2 O and 2 H in total
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The salt we add to food is $\text{NaCl}$. Calculate its molecular mass (atomic masses: $\text{Na} = 23\ \text{u}$; $\text{Cl} = 35.5\ \text{u}$).

The salt we add to food is $\text{NaCl}$. Calculate its molecular mass (atomic masses: $\text{Na} = 23\ \text{u}$; $\text{Cl} = 35.5\ \text{u}$).

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Mollusk shells and school chalk are made of calcium carbonate, $\text{CaCO}3$. The figure shows the atoms that form it. Calculate its molecular mass (atomic masses:…

Mollusk shells and school chalk are made of calcium carbonate, $\text{CaCO}_3$. The figure shows the atoms that form it.

Ca C O O O 40 u 12 u 16 u 16 u 16 u molecular mass = ?

Calculate its molecular mass (atomic masses: $\text{Ca} = 40\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

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Slaked lime, which is used in construction and vegetable gardens, has the formula $\text{Ca(OH)}2$. The figure shows its structure. Calculate its molecular mass…

Slaked lime, which is used in construction and vegetable gardens, has the formula $\text{Ca(OH)}_2$. The figure shows its structure.

Ca = 40 u · O = 16 u · H = 1 u Ca O H O H ×2 molecular mass = ?

Calculate its molecular mass carefully: the subscript $2$ outside the parentheses multiplies everything inside it (atomic masses: $\text{Ca} = 40\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{H} = 1\ \text{u}$).

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Glucose, $\text{C}6\text{H}{12}\text{O}6$, is the sugar that your muscles use when you play sports. Calculate its molecular mass (atomic masses:…

Glucose, $\text{C}_6\text{H}_{12}\text{O}_6$, is the sugar that your muscles use when you play sports. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

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Sulfuric acid, $\text{H}2\text{SO}4$, is used in car batteries. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{S} = 32\ \text{u}$;…

Sulfuric acid, $\text{H}_2\text{SO}_4$, is used in car batteries. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{S} = 32\ \text{u}$; $\text{O} = 16\ \text{u}$).

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Comparing masses

Once you know how to calculate molecular masses, you can compare substances with each other: how many times heavier one is than another, or which is the lightest in a group.

Bar chart comparing the molecular masses of hydrogen (H₂, 2 u), nitrogen (N₂, 28 u) and oxygen (O₂, 32 u). Molecular mass (u) 32 16 0 H₂ (2 u) N₂ (28 u) O₂ (32 u) Hydrogen Nitrogen Oxygen
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Nitrogen gas, $\text{N}2$, is used to fill bags of potato chips to keep them crunchy. Calculate its molecular mass (atomic mass: $\text{N} = 14\ \text{u}$).

Nitrogen gas, $\text{N}_2$, is used to fill bags of potato chips to keep them crunchy. Calculate its molecular mass (atomic mass: $\text{N} = 14\ \text{u}$).

Solve
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An oxygen molecule, $\text{O}2$, weighs $32\ \text{u}$ and a nitrogen molecule, $\text{N}2$, weighs $28\ \text{u}$. A hydrogen molecule, $\text{H}2$, weighs only…

An oxygen molecule, $\text{O}_2$, weighs $32\ \text{u}$ and a nitrogen molecule, $\text{N}_2$, weighs $28\ \text{u}$. A hydrogen molecule, $\text{H}_2$, weighs only $2\ \text{u}$.

  1. a) How many hydrogen molecules are needed together to weigh the same as one oxygen molecule?
  2. b) And to weigh the same as one nitrogen molecule?
Solve
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Order these molecules from lowest to highest molecular mass, calculating the mass of each one first: $\text{SO}2$, $\text{O}2$, $\text{CO}2$ and $\text{CH}4$ (atomic…

Order these molecules from lowest to highest molecular mass, calculating the mass of each one first: $\text{SO}_2$, $\text{O}_2$, $\text{CO}_2$ and $\text{CH}_4$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{S} = 32\ \text{u}$).

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The natural gas used in stoves is methane, $\text{CH}4$, and the ammonia in some cleaning products is $\text{NH}3$. The figure shows their molecules. a) Calculate the…

The natural gas used in stoves is methane, $\text{CH}_4$, and the ammonia in some cleaning products is $\text{NH}_3$. The figure shows their molecules.

H = 1 u · C = 12 u · N = 14 u C H H H H M = ? methane N H H H M = ? ammonia
  1. a) Calculate the molecular mass of each one.
  2. b) Which of the two molecules has a greater mass?

(Atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{N} = 14\ \text{u}$.)

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A glucose molecule, $\text{C}6\text{H}{12}\text{O}6$, has a molecular mass of $180\ \text{u}$. a) How many water molecules ($18\ \text{u}$) weigh the same as one glucose…

A glucose molecule, $\text{C}_6\text{H}_{12}\text{O}_6$, has a molecular mass of $180\ \text{u}$.

  1. a) How many water molecules ($18\ \text{u}$) weigh the same as one glucose molecule?
  2. b) How many hydrogen molecules ($2\ \text{u}$)?
  3. c) Do the same calculation for oxygen ($32\ \text{u}$). Do you get an integer? Explain what it means if it does not come out exact.
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Compare without a balance, using only calculations: a) Which weighs more: two water molecules ($18\ \text{u}$ each) or one oxygen molecule ($32\ \text{u}$)? b) What…

Compare without a balance, using only calculations:

  1. a) Which weighs more: two water molecules ($18\ \text{u}$ each) or one oxygen molecule ($32\ \text{u}$)?
  2. b) What about three nitrogen molecules ($28\ \text{u}$ each) or two of carbon dioxide ($44\ \text{u}$ each)?
  3. c) Explain the procedure you followed to compare them.
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Percent of mass and groups of molecules

You can also ask how much of a molecule's mass comes from one element, or how much a whole bag of molecules weighs. The percent of mass is the part divided by the whole, times $100$. For a group, multiply the mass of one molecule by the number of molecules.

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The molecular mass of calcium carbonate, $\text{CaCO}3$, is $100\ \text{u}$. The bar in the figure shows how that mass is divided. a) Calculate what percentage of the…

The molecular mass of calcium carbonate, $\text{CaCO}_3$, is $100\ \text{u}$. The bar in the figure shows how that mass is divided.

Ca: 40 u C: 12 u O: 48 u % = ? % = ? % = ? total molecular mass = 100 u
  1. a) Calculate what percentage of the mass corresponds to calcium ($40\ \text{u}$).
  2. b) Do the same for carbon ($12\ \text{u}$) and for oxygen (three atoms of $16\ \text{u}$ in total).
  3. c) Check that the three percentages add up to $100\ \%$.
Solve
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Sulfur dioxide, $\text{SO}2$, is released by volcanoes and is also used as a preservative in dried fruit. a) Calculate its molecular mass ($\text{S} = 32\ \text{u}$;…

Sulfur dioxide, $\text{SO}_2$, is released by volcanoes and is also used as a preservative in dried fruit.

  1. a) Calculate its molecular mass ($\text{S} = 32\ \text{u}$; $\text{O} = 16\ \text{u}$).
  2. b) What percentage of the mass of the molecule is sulfur? And oxygen?
  3. c) Explain why the two percentages must add up to exactly $100\ \%$.
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Two closed bags each contain $100$ molecules: the first contains methane, $\text{CH}4$, and the second sulfur dioxide, $\text{SO}2$ (atomic masses:…

Two closed bags each contain $100$ molecules: the first contains methane, $\text{CH}_4$, and the second sulfur dioxide, $\text{SO}_2$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{S} = 32\ \text{u}$).

  1. a) Calculate the molecular mass of each gas.
  2. b) How much does the contents of each bag weigh, in $\text{u}$?
  3. c) How many times more does one bag weigh than the other? Justify your answer.
Solve

Summary

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