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Matter · Elements and compounds

Atomic mass and molecular mass

When you drink a glass of water from the tap in Cork or Galway, you are drinking an unimaginably huge number of molecules: a single atom is far too light for any balance to notice. That is why, in chemistry, atoms are not weighed in grams, but with a unit made to their size. We will come back to that glass of water at the end.

Atomic mass: how much does an atom weigh?

If you try to weigh a speck of dust on a kitchen scale, it reads zero because it is far too light, but if you compare two tiny objects with each other you can tell which one weighs twice as much: how do we assign a mass to atoms if there is no balance capable of weighing them one at a time?

Comparison of atomic masses: a hydrogen atom of 1 u next to an oxygen atom of 16 u, which weighs 16 times more. H Hydrogen 1 u O Oxygen 16 u ×16 Oxygen weighs 16 times more than hydrogen

Hydrogen, the lightest atom, weighs about $1\ \text{u}$. Carbon weighs $12\ \text{u}$, about $12$ times more; oxygen weighs $16\ \text{u}$, about $16$ times more. (The unit itself is defined as one twelfth of the mass of a carbon-12 atom.)

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What is the atomic mass of an element and in which unit is it measured? Look up the atomic mass of carbon and oxygen in the periodic table, and state which of the two…

What is the atomic mass of an element and in which unit is it measured? Look up the atomic mass of carbon and oxygen in the periodic table, and state which of the two atoms weighs more.

Solve
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These are the atomic masses of four elements: $\text{H} = 1\ \text{u}$, $\text{C} = 12\ \text{u}$, $\text{N} = 14\ \text{u}$ and $\text{O} = 16\ \text{u}$. a) How many…

These are the atomic masses of four elements: $\text{H} = 1\ \text{u}$, $\text{C} = 12\ \text{u}$, $\text{N} = 14\ \text{u}$ and $\text{O} = 16\ \text{u}$.

  1. a) How many times heavier is a carbon atom than a hydrogen atom?
  2. b) And a nitrogen atom than a hydrogen atom?
Solve

Molecular mass: adding up atoms

If you join three building pieces together to make a block, the whole block weighs exactly the same as its three pieces added up separately: does the same happen when several atoms bond to form a molecule?

Water molecule H₂O: one oxygen atom of 16 u bonded to two hydrogen atoms of 1 u each; the molecular mass is the sum, 18 u. H H O 1 H atom 1 u 1 H atom 1 u 1 O atom: 16 u M = 1 + 1 + 16 = 18 u
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The oxygen we breathe travels through the air forming molecules of $\text{O}2$. If the atomic mass of oxygen is $16\ \text{u}$, calculate the molecular mass of…

The oxygen we breathe travels through the air forming molecules of $\text{O}_2$. If the atomic mass of oxygen is $16\ \text{u}$, calculate the molecular mass of $\text{O}_2$.

Solve
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The figure shows the model of a water molecule. Calculate the molecular mass of water, $\text{H}2\text{O}$ (atomic masses: $\text{H} = 1\ \text{u}$;…

The figure shows the model of a water molecule.

O H H 16 u 1 u 1 u molecular mass = ?

Calculate the molecular mass of water, $\text{H}_2\text{O}$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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The gas that forms bubbles in soft drinks is carbon dioxide, $\text{CO}2$. The figure shows its molecule. Calculate its molecular mass (atomic masses:…

The gas that forms bubbles in soft drinks is carbon dioxide, $\text{CO}_2$. The figure shows its molecule.

O C O 16 u 12 u 16 u molecular mass = ?

Calculate its molecular mass (atomic masses: $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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Explain in your own words the difference between atomic mass and molecular mass, and give an example of each.

Explain in your own words the difference between atomic mass and molecular mass, and give an example of each.

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Calculating with subscripts and brackets

An element's subscript tells you how many atoms of that element there are. When there are brackets with a subscript outside, that number multiplies everything inside.

Formula of calcium hydroxide, with an arrow showing that the outer subscript multiplies all the elements inside the brackets. Ca(OH) 2 the 2 multiplies O and H: 2 O and 2 H in total
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The salt we add to food is $\text{NaCl}$. Calculate its molecular mass (atomic masses: $\text{Na} = 23\ \text{u}$; $\text{Cl} = 35.5\ \text{u}$).

The salt we add to food is $\text{NaCl}$. Calculate its molecular mass (atomic masses: $\text{Na} = 23\ \text{u}$; $\text{Cl} = 35.5\ \text{u}$).

Solve
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Mollusc shells and school chalk are made of calcium carbonate, $\text{CaCO}3$. The figure shows the atoms that form it. Calculate its molecular mass (atomic masses:…

Mollusc shells and school chalk are made of calcium carbonate, $\text{CaCO}_3$. The figure shows the atoms that form it.

Ca C O O O 40 u 12 u 16 u 16 u 16 u molecular mass = ?

Calculate its molecular mass (atomic masses: $\text{Ca} = 40\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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Glucose, $\text{C}6\text{H}{12}\text{O}6$, is the sugar that your muscles use when you do sport. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$;…

Glucose, $\text{C}_6\text{H}_{12}\text{O}_6$, is the sugar that your muscles use when you do sport. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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Sulphuric acid, $\text{H}2\text{SO}4$, is used in car batteries. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{S} = 32\ \text{u}$;…

Sulphuric acid, $\text{H}_2\text{SO}_4$, is used in car batteries. Calculate its molecular mass (atomic masses: $\text{H} = 1\ \text{u}$; $\text{S} = 32\ \text{u}$; $\text{O} = 16\ \text{u}$).

Solve
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Slaked lime, which is used in building work and vegetable gardens, has the formula $\text{Ca(OH)}2$. The figure shows its structure. Calculate its molecular mass…

Slaked lime, which is used in building work and vegetable gardens, has the formula $\text{Ca(OH)}_2$. The figure shows its structure.

Ca = 40 u · O = 16 u · H = 1 u Ca O H O H ×2 molecular mass = ?

Calculate its molecular mass carefully: the subscript $2$ outside the bracket multiplies everything inside it (atomic masses: $\text{Ca} = 40\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{H} = 1\ \text{u}$).

Solve

Comparing masses

Once you know how to calculate molecular masses, you can compare substances with each other: how many times heavier one is than another, or which is the lightest in a group.

Bar chart comparing the molecular masses of hydrogen (H₂, 2 u), nitrogen (N₂, 28 u) and oxygen (O₂, 32 u). Molecular mass (u) 32 16 0 H₂ (2 u) N₂ (28 u) O₂ (32 u) Hydrogen Nitrogen Oxygen

Working backwards, percentages and averages

The same idea works in reverse, and it also lets you say how much of a molecule's mass comes from each element.

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Nitrogen gas, $\text{N}2$, is used to fill bags of crisps to keep them crunchy. Calculate its molecular mass (atomic mass: $\text{N} = 14\ \text{u}$).

Nitrogen gas, $\text{N}_2$, is used to fill bags of crisps to keep them crunchy. Calculate its molecular mass (atomic mass: $\text{N} = 14\ \text{u}$).

Solve
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The natural gas used in cookers is methane, $\text{CH}4$, and the ammonia in some cleaning products is $\text{NH}3$. The figure shows their molecules. a) Calculate the…

The natural gas used in cookers is methane, $\text{CH}_4$, and the ammonia in some cleaning products is $\text{NH}_3$. The figure shows their molecules.

H = 1 u · C = 12 u · N = 14 u C H H H H M = ? methane N H H H M = ? ammonia
  1. a) Calculate the molecular mass of each one.
  2. b) Which of the two molecules weighs more?

(Atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{N} = 14\ \text{u}$.)

Solve
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The molecular mass of $\text{CO}2$ is $44\ \text{u}$ and the atomic mass of oxygen is $16\ \text{u}$. Look at the model in the figure. Without looking at the periodic…

The molecular mass of $\text{CO}_2$ is $44\ \text{u}$ and the atomic mass of oxygen is $16\ \text{u}$. Look at the model in the figure.

total molecular mass = 44 u O C O 16 u C = ? 16 u

Without looking at the periodic table, deduce the atomic mass of carbon and explain how you worked it out.

Solve
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An oxygen molecule, $\text{O}2$, weighs $32\ \text{u}$ and a nitrogen molecule, $\text{N}2$, weighs $28\ \text{u}$. A hydrogen molecule, $\text{H}2$, weighs only…

An oxygen molecule, $\text{O}_2$, weighs $32\ \text{u}$ and a nitrogen molecule, $\text{N}_2$, weighs $28\ \text{u}$. A hydrogen molecule, $\text{H}_2$, weighs only $2\ \text{u}$.

  1. a) How many hydrogen molecules are needed together to weigh the same as one oxygen molecule?
  2. b) And to weigh the same as one nitrogen molecule?
Solve
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Order these molecules from lowest to highest molecular mass, calculating the mass of each one first: $\text{SO}2$, $\text{O}2$, $\text{CO}2$ and $\text{CH}4$ (atomic…

Order these molecules from lowest to highest molecular mass, calculating the mass of each one first: $\text{SO}_2$, $\text{O}_2$, $\text{CO}_2$ and $\text{CH}_4$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{S} = 32\ \text{u}$).

Solve
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The molecular mass of calcium carbonate, $\text{CaCO}3$, is $100\ \text{u}$. The bar in the figure shows how that mass is divided. a) Calculate what percentage of the…

The molecular mass of calcium carbonate, $\text{CaCO}_3$, is $100\ \text{u}$. The bar in the figure shows how that mass is divided.

Ca: 40 u C: 12 u O: 48 u % = ? % = ? % = ? total molecular mass = 100 u
  1. a) Calculate what percentage of the mass corresponds to calcium ($40\ \text{u}$).
  2. b) Do the same for carbon ($12\ \text{u}$) and for oxygen (three atoms of $16\ \text{u}$ in total).
  3. c) Check that the three percentages add up to $100\ \%$.
Solve
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Sulfur dioxide, $\text{SO}2$, is released by volcanoes and is also used as a preservative in dried fruit. a) Calculate its molecular mass ($\text{S} = 32\ \text{u}$;…

Sulfur dioxide, $\text{SO}_2$, is released by volcanoes and is also used as a preservative in dried fruit.

  1. a) Calculate its molecular mass ($\text{S} = 32\ \text{u}$; $\text{O} = 16\ \text{u}$).
  2. b) What percentage of the mass of the molecule is sulfur? And oxygen?
  3. c) Explain why the two percentages must add up to exactly $100\ \%$.
Solve
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The atomic mass of chlorine shown in the periodic table is $35.5\ \text{u}$, but no chlorine atom weighs exactly that: some chlorine atoms weigh $35\ \text{u}$ and…

The atomic mass of chlorine shown in the periodic table is $35.5\ \text{u}$, but no chlorine atom weighs exactly that: some chlorine atoms weigh $35\ \text{u}$ and others weigh $37\ \text{u}$ (these are called isotopes). The figure represents the two types of atoms.

some atoms Cl 35 u other atoms Cl 37 u the periodic table says: 35.5 u
  1. a) Explain in your own words how it is possible for the atomic mass in the periodic table to be $35.5\ \text{u}$.
  2. b) Reason which of the two types of chlorine atoms will be more abundant in nature.
Solve
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A salt formed by a metal and chlorine has the formula $\text{XCl}2$ and a molecular mass of $111\ \text{u}$. The figure shows its model. a) Knowing that…

A salt formed by a metal and chlorine has the formula $\text{XCl}_2$ and a molecular mass of $111\ \text{u}$. The figure shows its model.

X X = ? Cl 35.5 u Cl 35.5 u total molecular mass = 111 u
  1. a) Knowing that $\text{Cl} = 35.5\ \text{u}$, calculate the atomic mass of element $\text{X}$.
  2. b) Look it up in the periodic table and identify the element.
  3. c) Write the full name of the salt.
Solve
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A glucose molecule, $\text{C}6\text{H}{12}\text{O}6$, has a molecular mass of $180\ \text{u}$. a) How many water molecules ($18\ \text{u}$) weigh the same as one glucose…

A glucose molecule, $\text{C}_6\text{H}_{12}\text{O}_6$, has a molecular mass of $180\ \text{u}$.

  1. a) How many water molecules ($18\ \text{u}$) weigh the same as one glucose molecule?
  2. b) How many hydrogen molecules ($2\ \text{u}$)?
  3. c) Do the same calculation for oxygen ($32\ \text{u}$). Do you get an integer? Explain what it means if it does not come out exact.
Solve
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Air is approximately $80\ \%$ nitrogen $\text{N}2$ ($28\ \text{u}$) and $20\ \%$ oxygen $\text{O}2$ ($32\ \text{u}$). The figure represents a sample of air. a) Calculate…

Air is approximately $80\ \%$ nitrogen $\text{N}_2$ ($28\ \text{u}$) and $20\ \%$ oxygen $\text{O}_2$ ($32\ \text{u}$). The figure represents a sample of air.

N₂ (28 u) O₂ (32 u)
  1. a) Calculate the average molecular mass of air. Hint: weight each mass according to its percentage.
  2. b) Does a molecule of $\text{CO}_2$ ($44\ \text{u}$) weigh more or less than an "average" molecule of air?
  3. c) Use the result to reason why, in a closed room without draughts where $\text{CO}_2$ is being released (for example, a cellar where grape must is fermenting), this gas tends to accumulate near the floor.
Solve
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Compare without a balance, using only calculations: a) Which weighs more: two water molecules ($18\ \text{u}$ each) or one oxygen molecule ($32\ \text{u}$)? b) What…

Compare without a balance, using only calculations:

  1. a) Which weighs more: two water molecules ($18\ \text{u}$ each) or one oxygen molecule ($32\ \text{u}$)?
  2. b) What about three nitrogen molecules ($28\ \text{u}$ each) or two of carbon dioxide ($44\ \text{u}$ each)?
  3. c) Explain the procedure you followed to compare them.
Solve
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Two closed bags each contain $100$ molecules: the first contains methane, $\text{CH}4$, and the second sulfur dioxide, $\text{SO}2$ (atomic masses:…

Two closed bags each contain $100$ molecules: the first contains methane, $\text{CH}_4$, and the second sulfur dioxide, $\text{SO}_2$ (atomic masses: $\text{H} = 1\ \text{u}$; $\text{C} = 12\ \text{u}$; $\text{O} = 16\ \text{u}$; $\text{S} = 32\ \text{u}$).

  1. a) Calculate the molecular mass of each gas.
  2. b) How much does the contents of each bag weigh, in $\text{u}$?
  3. c) How many times more does one bag weigh than the other? Justify your answer.
Solve

Summary

Back to the glass of water: one $\text{H}_2\text{O}$ molecule weighs just $18\ \text{u}$, so it takes a huge number of molecules to make even one drop.

See all the exercises in this section