The particle model of matter
A piece of ice keeps its shape in your hand, but the water it melts into takes the shape of the glass, and if it evaporates, the vapour spreads through the whole kitchen. It is the same substance, water, behaving in three different ways. The explanation lies in something too small to see: its particles.
All matter is made of particles in motion
When someone opens a bag of freshly made chips or crisps at the back of the classroom, you soon smell them, even with the windows shut and no draught: how do the particles of the smell get across the room?
Move the temperature slider and watch: the particles (the blue dots) change the way they move depending on the state. This is a model: a simplified picture that is easier to study than the real thing.
When making a soft drink, you use tap water, put in some ice cubes, and at the back of the kitchen, steam comes out of a pot. Name the three states in which water can be…
When making a soft drink, you use tap water, put in some ice cubes, and at the back of the kitchen, steam comes out of a pot. Name the three states in which water can be found and write an everyday example for each, different from the ones shown here.
Complete the sentence with the missing words: "According to kinetic-molecular theory, all matter is made up of very small $\dots$ that are in continuous $\dots$." Then…
Complete the sentence with the missing words: "According to kinetic-molecular theory, all matter is made up of very small $\dots$ that are in continuous $\dots$." Then explain in your own words why we cannot see those particles.
Why solids have their own shape and volume
Aoife leaves a stone she collected at the beach on her bedroom shelf. The stone does not change shape or size, wherever it is. The figure shows how particles are…
Aoife leaves a stone she collected at the beach on her bedroom shelf. The stone does not change shape or size, wherever it is. The figure shows how particles are arranged inside a solid like this stone.
Explain, using kinetic-molecular theory, why solids have a fixed shape and volume. Think about how their particles are joined together and how they move.
In a solid, particles vibrate almost without changing position; in a liquid, they slide over one another; in a gas, they move freely throughout the container. Match each…
In a solid, particles vibrate almost without changing position; in a liquid, they slide over one another; in a gas, they move freely throughout the container. Match each type of motion to one of these observations and justify the relationship:
- a) An iron block always keeps its shape.
- b) Water from a bottle can be poured into a glass.
- c) Air in a balloon fills its entire interior.
Why liquids take the shape of their container
Cian pours juice from a wide glass into a narrow bottle: the juice changes shape, but the amount of juice remains the same. The figure shows the juice in both…
Cian pours juice from a wide glass into a narrow bottle: the juice changes shape, but the amount of juice remains the same. The figure shows the juice in both containers.
Explain why a liquid has a fixed volume but no fixed shape, thinking about how its particles move.
Aoife covers the outlet of a syringe filled with air with her finger and pushes the plunger: the air can be compressed significantly. If she fills the syringe with water…
Aoife covers the outlet of a syringe filled with air with her finger and pushes the plunger: the air can be compressed significantly. If she fills the syringe with water and repeats the test, the plunger barely moves. The figure represents the two tests.
What difference is there between the particles of a gas and those of a liquid that explains this result?
Hugo carefully drops an ink droplet into a glass of water without stirring. After a while, all the water has become coloured, as shown in the figure. What phenomenon has…
Hugo carefully drops an ink droplet into a glass of water without stirring. After a while, all the water has become coloured, as shown in the figure.
What phenomenon has occurred? Explain it using kinetic-molecular theory: what do the ink particles and the water particles do?
Why gases fill everything
If you burst an inflated balloon, the air rushes out and its smell spreads through the whole room straight away: why does a gas never stay still, or keep the shape and volume of the balloon once it is released?
When inflating a ball, the air that enters ends up filling all of its interior. It does not matter whether the ball is spherical, like a football, or oval, like a rugby…
When inflating a ball, the air that enters ends up filling all of its interior. It does not matter whether the ball is spherical, like a football, or oval, like a rugby ball: the air always fills it completely. In the figure, its particles are represented inside the ball.
Explain what the particles of a gas do and why gases have neither a fixed shape nor a fixed volume.
A newly inflated air mattress is hard: when you press it with your hand, you feel resistance. Explain, using kinetic-molecular theory, what the air particles do against…
A newly inflated air mattress is hard: when you press it with your hand, you feel resistance. Explain, using kinetic-molecular theory, what the air particles do against the inner walls of the mattress and why that explains why we feel this resistance.
A small camping gas canister holds enough gas to fill many large balloons. How is it possible for so much gas to fit in such a small container? Relate this to the empty…
A small camping gas canister holds enough gas to fill many large balloons. How is it possible for so much gas to fit in such a small container? Relate this to the empty spaces between the particles of a gas.
Gas pressure: countless tiny collisions
When you pump up a football before a Gaelic football match, it goes from soft to hard. Nothing solid was added, only more air. Where does the push on the inside of the ball come from?
Aoife compares two balls: one deflated, which is soft, and another newly inflated, which is hard. Inside the second one there are many more air particles, as shown in…
Aoife compares two balls: one deflated, which is soft, and another newly inflated, which is hard. Inside the second one there are many more air particles, as shown in the figure.
Explain, thinking about the collisions of particles against the walls of the ball, why the inflated ball is harder.
Aoife fills a syringe with $10\ \text{mL}$ of air, covers the outlet with her finger and pushes the plunger until the air is reduced to $5\ \text{mL}$. a) Has the number…
Aoife fills a syringe with $10\ \text{mL}$ of air, covers the outlet with her finger and pushes the plunger until the air is reduced to $5\ \text{mL}$.
- a) Has the number of air particles inside the syringe changed?
- b) What happens to the number of particle collisions against the walls per second?
- c) Does the air pressure increase or decrease? Reason all three answers.
Weather balloons that measure atmospheric weather are released half-inflated. As they rise, the external air pressure decreases, and the balloon expands more and more…
Weather balloons that measure atmospheric weather are released half-inflated. As they rise, the external air pressure decreases, and the balloon expands more and more until it bursts. The figure shows the balloon when released and at high altitude.
Explain, thinking about collisions of the particles inside and outside, why the balloon grows as the external pressure decreases.
Heating and cooling a gas
A sealed crisp packet left on a warm radiator puffs up like a small pillow. The amount of air inside has not changed, so what has?
A deodorant can reads: "Do not expose to temperatures exceeding $50\ ^\circ\text{C}$". The can is airtight and contains gas under pressure. Explain what happens to the…
A deodorant can reads: "Do not expose to temperatures exceeding $50\ ^\circ\text{C}$". The can is airtight and contains gas under pressure. Explain what happens to the gas particles when the can is heated and why the can might burst.
After a long bike ride on a hot day, Omar notices the tyres are harder than when he set off, without having used the pump and without punctures. Explain, using…
After a long bike ride on a hot day, Omar notices the tyres are harder than when he set off, without having used the pump and without punctures. Explain, using kinetic-molecular theory, what has happened to the air particles inside the tyres.
An empty, tightly sealed plastic bottle is left inside a car in the sun: after a while, it bulges, as if inflated. If you put it in the fridge for a few hours, it…
An empty, tightly sealed plastic bottle is left inside a car in the sun: after a while, it bulges, as if inflated. If you put it in the fridge for a few hours, it appears crumpled, collapsed inwards. Explain both changes using kinetic-molecular theory: what the internal air particles do in each case and what happens to the pressure.
Diffusion: particles travel on their own
Aoife puts perfume on her wrist in her bedroom and, after a short while, her brother smells it from the living room without any air current blowing. How did the perfume…
Aoife puts perfume on her wrist in her bedroom and, after a short while, her brother smells it from the living room without any air current blowing. How did the perfume particles reach her brother's nose? What is this phenomenon called?
If a small amount of gas escapes from a butane cylinder, it can be smelled throughout the kitchen in a few seconds. In contrast, a drop of ink in a glass of water takes…
If a small amount of gas escapes from a butane cylinder, it can be smelled throughout the kitchen in a few seconds. In contrast, a drop of ink in a glass of water takes several minutes to dye it completely. Why do you think diffusion is much faster in gases than in liquids? Think about the distance between particles and how free they are to move.
Design an experiment to verify that gas particles are in continuous motion using only a spray air freshener, a stopwatch and a tape measure. State: a) What you would do…
Design an experiment to verify that gas particles are in continuous motion using only a spray air freshener, a stopwatch and a tape measure. State:
- a) What you would do and what you would measure.
- b) What result you expect to obtain.
- c) What conclusion you would reach if the result confirms the theory.
Temperature, diffusion and evaporation
Wet clothes on the line dry much faster on a warm, breezy day in Kilkenny than on a cold, damp one. What do the particles have to do with it?
At Aoife's house, the hot soup that has just been served can be smelled from the hallway, but cold cucumber soup is barely noticeable until you bring your nose close to…
At Aoife's house, the hot soup that has just been served can be smelled from the hallway, but cold cucumber soup is barely noticeable until you bring your nose close to the plate. Explain the difference using kinetic-molecular theory: what effect does temperature have on the particles, and how does this influence the diffusion of the smell?
In the laboratory, Eric prepares two glasses: one with cold water from the fridge and another with hot water. He drops a drop of food colouring into each, at the same…
In the laboratory, Eric prepares two glasses: one with cold water from the fridge and another with hot water. He drops a drop of food colouring into each, at the same time and without stirring, as shown in the figure.
- a) Predict what will be observed in each glass after five minutes.
- b) Explain your prediction using kinetic-molecular theory.
- c) State a general conclusion relating temperature to the rate of diffusion.
A glass of water left forgotten on a window sill drops in level after a few weeks, even though no one drinks from it. Explain, using kinetic-molecular theory, what…
A glass of water left forgotten on a window sill drops in level after a few weeks, even though no one drinks from it. Explain, using kinetic-molecular theory, what happens to the faster particles on the surface of the water. Then, predict what would happen to the water level if the glass were hermetically sealed, and justify your answer.
Back to the start: The ice, the water in the glass and the vapour in the kitchen are exactly the same water particles; the only difference is that in the ice they vibrate in order in fixed positions, in the glass they slide over one another, and in the vapour they fly freely all around the room.