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Matter · States of matter

Changes of state

On a cold January morning in Galway you put some ice in a saucepan on the hob and, while it is melting, the thermometer stays stuck at $0\ ^{\circ}\mathrm{C}$ for quite a while, even though the heat is still on. Where does that heat go if the temperature does not rise?

The six changes of state

You take an ice cube out of the freezer for your glass of cordial, after a while it turns into a puddle of liquid water and, if you leave it in the sun for several days, the glass ends up dry: how can matter change from one form to another without ceasing to be the same substance?

Diagram of the three states of matter and the names of the six changes of state shown with arrows solid liquid gas melting freezing vaporisation condensation sublimation deposition

Key idea: the mass of a substance does not change during a change of state. When ice melts, the particles are the same, only arranged differently, so no matter is gained or lost. This links to the plateau: while ice melts, the heat going in is used to loosen the particles from their fixed positions, not to make them move faster, so the temperature stays at $0\ ^{\circ}\mathrm{C}$ and the mass stays the same.

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Copy and complete the diagram with the name of each change of state: a) From solid to liquid: $\dots$ b) From liquid to gas: $\dots$ c) From gas to liquid: $\dots$ d)…

Copy and complete the diagram with the name of each change of state:

GAS SOLID LIQUID a) ? d) ? b) ? c) ? e) ?
  1. a) From solid to liquid: $\dots$
  2. b) From liquid to gas: $\dots$
  3. c) From gas to liquid: $\dots$
  4. d) From liquid to solid: $\dots$
  5. e) From solid to gas, without passing through liquid: $\dots$
Solve
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In a soft drink with ice, the cubes get smaller and smaller until they disappear. What change of state has the ice undergone? State the initial state, the final state…

In a soft drink with ice, the cubes get smaller and smaller until they disappear. What change of state has the ice undergone? State the initial state, the final state and the name of the change.

Solve
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Mothballs placed in wardrobes against moths wear away gradually without wetting anything around them: they pass directly from solid to gas. What is this change of state…

Mothballs placed in wardrobes against moths wear away gradually without wetting anything around them: they pass directly from solid to gas. What is this change of state called?

Solve
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Identify the change of state occurring in each case and reason whether the substance absorbs heat from the surroundings or releases it: a) Morning dew: droplets of water…

Identify the change of state occurring in each case and reason whether the substance absorbs heat from the surroundings or releases it:

  1. a) Morning dew: droplets of water on grass.
  2. b) Wet clothes drying in the sun.
  3. c) Liquid paraffin of a candle becoming solid when extinguished.
Solve

Melting and freezing: the melting point

Move the slider past $0\ ^{\circ}\mathrm{C}$: you will see the particles change from vibrating in place to sliding freely past one another. That temperature value is the melting point of this substance.

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To make ice at home, Leo fills an ice cube tray with water and puts it in the freezer. What change of state does the water undergo? Write its name and its direction…

To make ice at home, Leo fills an ice cube tray with water and puts it in the freezer. What change of state does the water undergo? Write its name and its direction (from which state to which state).

Solve
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At what temperature does ice melt? And at what temperature does water boil at sea level? Express them in degrees Celsius.

At what temperature does ice melt? And at what temperature does water boil at sea level? Express them in degrees Celsius.

Solve
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Cian heats a saucepan with ice and water and observes the thermometer: while there is still un-melted ice, the temperature does not rise. The figure shows the apparatus.…

Cian heats a saucepan with ice and water and observes the thermometer: while there is still un-melted ice, the temperature does not rise. The figure shows the apparatus.

ice + water

What happens to the temperature of a substance while a change of state is taking place? Does it rise, fall or remain constant?

Solve

Vaporisation and condensation: evaporation and boiling

Wet clothes on a line in Cork dry even on a cool day, but a pot on the cooker only boils at $100\ ^{\circ}\mathrm{C}$. Both are liquid turning to gas: what is the difference?

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Grandma's pot is boiling and the kitchen thermometer reads $100\ ^\circ\text{C}$. You turn the heat up to maximum and steam comes out more strongly, but the thermometer…

Grandma's pot is boiling and the kitchen thermometer reads $100\ ^\circ\text{C}$. You turn the heat up to maximum and steam comes out more strongly, but the thermometer still reads $100\ ^\circ\text{C}$, as shown in the figure.

100 °C
  1. a) What change of state is occurring?
  2. b) If more heat arrives, why does the temperature not rise? What is this energy being used for?
Solve
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A puddle in the street dries in the sun at $20\ ^\circ\text{C}$ without the water boiling. In contrast, water in a pot only boils when it reaches $100\ ^\circ\text{C}$.…

A puddle in the street dries in the sun at $20\ ^\circ\text{C}$ without the water boiling. In contrast, water in a pot only boils when it reaches $100\ ^\circ\text{C}$. In both cases, water changes from liquid to gas. Explain the difference between evaporation and boiling: which part of the liquid is transformed into gas in each case, and at what temperatures can each occur?

Solve
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After mopping the kitchen floor, you want it to dry as quickly as possible. Will it dry faster on a hot day or a cold day? Does opening the window to let the air…

After mopping the kitchen floor, you want it to dry as quickly as possible. Will it dry faster on a hot day or a cold day? Does opening the window to let the air circulate help? Give two reasons, thinking about what helps the water particles escape from the floor's surface.

Solve
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When a wound is disinfected with rubbing alcohol, the skin becomes dry in seconds and you feel a cold sensation in the area. a) What change of state does the alcohol…

When a wound is disinfected with rubbing alcohol, the skin becomes dry in seconds and you feel a cold sensation in the area.

  1. a) What change of state does the alcohol undergo on the skin?
  2. b) Vaporisation requires heat to occur: where does the alcohol get this heat from? Why do you feel cold?
Solve
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In a mountain shelter at an altitude of $2000\ \text{m}$, water boils at around $93\ ^\circ\text{C}$, because the air pressure is lower than at sea level. a) Do you…

In a mountain shelter at an altitude of $2000\ \text{m}$, water boils at around $93\ ^\circ\text{C}$, because the air pressure is lower than at sea level.

  1. a) Do you think a boiled egg cooks faster or slower there than on the beach? Justify your answer.
  2. b) In a pressure cooker, the opposite happens: water boils above $100\ ^\circ\text{C}$. Why does food cook faster in it?
Solve

Sublimation and deposition

A bathroom air-freshener block gets smaller every week until it disappears completely, but it never leaves any liquid around it: how can a solid evaporate without passing through the liquid state?

Some substances sublime because, at normal air pressure, they pass from solid to gas without a liquid stage. Solid carbon dioxide (dry ice) does this at $-78\ ^{\circ}\mathrm{C}$, and so do mothballs (naphthalene) slowly at room temperature. For carbon dioxide, a liquid only appears if the pressure is much higher (above about 5 atm); naphthalene, by contrast, melts normally if it is heated above about $80\ ^{\circ}\mathrm{C}$.

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When boiling water in a kettle, steam comes out of the spout. What is the name of the change of state from liquid to gas? Give another everyday example in which this…

When boiling water in a kettle, steam comes out of the spout. What is the name of the change of state from liquid to gas? Give another everyday example in which this same change occurs.

Solve
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When taking a hot shower, the bathroom mirror fogs up and becomes covered in small droplets. What change of state does the water vapour undergo when touching the cold…

When taking a hot shower, the bathroom mirror fogs up and becomes covered in small droplets. What change of state does the water vapour undergo when touching the cold mirror? Write its name and its direction (from which state to which state).

Solve
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On a very cold morning, the windscreen of a car wakes up covered in frost: the water vapour in the air has turned directly into ice, without becoming a liquid first.…

On a very cold morning, the windscreen of a car wakes up covered in frost: the water vapour in the air has turned directly into ice, without becoming a liquid first. What change of state is this? How is it similar to and different from the formation of dew?

Solve
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After a snowfall, a cold, dry week follows, with the temperature not rising above $0\ ^\circ\text{C}$. Even so, the snow on the pavement shrinks day by day without…

After a snowfall, a cold, dry week follows, with the temperature not rising above $0\ ^\circ\text{C}$. Even so, the snow on the pavement shrinks day by day without wetting the ground. What change of state explains why the snow disappears without melting? Explain it.

Solve
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At concerts, dry ice (solid carbon dioxide, which is very cold) is used to create a white cloud covering the stage floor. a) Dry ice turns directly from solid into gas…

At concerts, dry ice (solid carbon dioxide, which is very cold) is used to create a white cloud covering the stage floor.

  1. a) Dry ice turns directly from solid into gas without melting: what is this change of state called?
  2. b) The white cloud is not carbon dioxide, which is invisible, but tiny water droplets that form when the water vapour in the air cools down beside it: what change of state does this water vapour undergo? Explain the complete chain of changes that produces the cloud.
Solve

Heating curves

You heat ice with a sensor that records the temperature every minute: you would expect a continuous rise, but you get a graph with completely flat steps where time keeps running and the temperature stands still: why does the thermometer stop if the heat is still on?

Graph of temperature against time when ice is heated: sloping section up to 0 °C, melting plateau at 0 °C, sloping section up to 100 °C and boiling plateau at 100 °C 100 °C 0 °C melting (plateau) boiling (plateau) ice ice + water liquid water water + vapour time temperature
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Aoife heats crushed ice coming out of the freezer at $-10\ ^\circ\text{C}$ and measures the temperature every minute: first it rises to $0\ ^\circ\text{C}$; then it…

Aoife heats crushed ice coming out of the freezer at $-10\ ^\circ\text{C}$ and measures the temperature every minute: first it rises to $0\ ^\circ\text{C}$; then it remains fixed at $0\ ^\circ\text{C}$ for $6\ \text{min}$ while water appears; finally it rises again. The figure shows the temperature-time graph Aoife obtains.

T (°C) t (min) 0 −10 6 min
  1. a) In which section is there only ice?
  2. b) What is happening during the horizontal section at $0\ ^\circ\text{C}$? In what state or states is the water in this section?
Solve
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In a laboratory experiment, a saucepan with ice at $-5\ ^\circ\text{C}$ is heated over a constant flame and the temperature is recorded every minute: the temperature…

In a laboratory experiment, a saucepan with ice at $-5\ ^\circ\text{C}$ is heated over a constant flame and the temperature is recorded every minute: the temperature rises and reaches $0\ ^\circ\text{C}$ at minute $2$; it stays at $0\ ^\circ\text{C}$ until minute $10$; then it rises again up to $100\ ^\circ\text{C}$, which it reaches at minute $20$, and remains there while the water boils.

  1. a) Describe what the temperature-time graph would look like: which rising sections and which horizontal sections (plateaus) it has, and at what temperatures they are.
  2. b) What state is the water in at minute $5$? And at minute $15$?
  3. c) How many minutes did the melting of the ice last?
  4. d) What is happening during each plateau? Why does the temperature not rise during them even though the flame remains on?
Solve
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When an unknown substance is heated, its temperature-time graph shows two plateaus: one at $50\ ^\circ\text{C}$ and another at $120\ ^\circ\text{C}$, as shown in the…

When an unknown substance is heated, its temperature-time graph shows two plateaus: one at $50\ ^\circ\text{C}$ and another at $120\ ^\circ\text{C}$, as shown in the figure.

T (°C) t (min) 50 120
  1. a) What does each plateau mean?
  2. b) What state is the substance in at $25\ ^\circ\text{C}$? And at $90\ ^\circ\text{C}$?
  3. c) Could it be water? Explain why melting and boiling points are used to identify substances.
Solve
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Ethyl alcohol boils at $78\ ^\circ\text{C}$. In the laboratory, you heat, at the same time and using the same flame, a beaker with water and another with the same amount…

Ethyl alcohol boils at $78\ ^\circ\text{C}$. In the laboratory, you heat, at the same time and using the same flame, a beaker with water and another with the same amount of alcohol, both starting at the same temperature.

  1. a) Which of the two reaches its boiling plateau first?
  2. b) When both are boiling, which one is at a higher temperature?
  3. c) What characteristic property of each substance does this experiment demonstrate? What can knowing it be useful for?
Solve

Back to the beginning: The heat supplied while the thermometer reads $0\ ^{\circ}\mathrm{C}$ does not raise the temperature because it does not speed up the particles, but is used entirely to overcome the forces between the particles that hold them fixed in place in the ice.

Summary

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