Evidence of a chemical reaction
You mix bicarbonate of soda with vinegar and the glass instantly fills with bubbles. Something has really changed, not just its appearance. How can you tell, without a full laboratory, that a new substance has really formed?
Release of gas
You drop an effervescent tablet into a glass of water: instantly it fills with bubbles that escape into the air, and the mass of the open glass decreases. Where does that gas come from if you started only with a compact solid and a liquid?
You mix a spoonful of bicarbonate of soda with vinegar in a glass and, instantly, it fills with bubbles and intense effervescence. What evidence of a chemical reaction…
You mix a spoonful of bicarbonate of soda with vinegar in a glass and, instantly, it fills with bubbles and intense effervescence. What evidence of a chemical reaction are you observing? What is being formed?
Pizza dough contains yeast and, when left to rest for a while, it doubles in size and becomes full of small holes. What evidence of a chemical change causes the dough to…
Pizza dough contains yeast and, when left to rest for a while, it doubles in size and becomes full of small holes. What evidence of a chemical change causes the dough to rise? What happens to the ingredients in the mixture?
A granular drain unblocker, when poured down the sink with water, forms a lot of foam and, furthermore, the pipe becomes warm to the touch. Identify the two pieces of…
A granular drain unblocker, when poured down the sink with water, forms a lot of foam and, furthermore, the pipe becomes warm to the touch. Identify the two pieces of evidence of a chemical reaction shown by the product and explain what each one indicates.
Formation of a precipitate
You add a few drops of a completely colourless liquid to another equally transparent liquid and, suddenly, the mixture turns cloudy and opaque like milk. How can a dense solid form from two transparent liquids?
In the laboratory, you mix two clear, colourless liquids and suddenly a yellow solid appears and settles at the bottom of the test tube, as shown in the diagram. What is…
In the laboratory, you mix two clear, colourless liquids and suddenly a yellow solid appears and settles at the bottom of the test tube, as shown in the diagram.
What is this solid that forms called? Why does its appearance indicate that a chemical reaction has taken place?
A farmer analyses irrigation water from his vegetable patch: he adds a few drops of a reagent to a sample and, if a white powder appears at the bottom of the tube, he…
A farmer analyses irrigation water from his vegetable patch: he adds a few drops of a reagent to a sample and, if a white powder appears at the bottom of the tube, he knows that the water contains an excess of a certain substance.
- a) What evidence of a chemical reaction does this test rely on?
- b) Why does the appearance of that powder prove that a new substance has been formed?
Change of colour
You slice an avocado to make guacamole and, if it is not eaten promptly, its surface turns brown. What evidence of a chemical reaction is this? Do you think only the…
You slice an avocado to make guacamole and, if it is not eaten promptly, its surface turns brown. What evidence of a chemical reaction is this? Do you think only the colour has changed or have new substances also been formed?
Red cabbage juice turns pink if you add a few drops of lemon juice and greenish if you add a soap solution, as shown in the diagram. a) What chemical evidence does this…
Red cabbage juice turns pink if you add a few drops of lemon juice and greenish if you add a soap solution, as shown in the diagram.
- a) What chemical evidence does this kitchen trick rely on?
- b) How can a juice that behaves like this be useful in the laboratory?
A tomato stain on Daniela's white T-shirt disappears when bleach is applied, but the treated area never returns to its original state, no matter how much she washes it…
A tomato stain on Daniela's white T-shirt disappears when bleach is applied, but the treated area never returns to its original state, no matter how much she washes it afterwards.
- a) What evidence of a chemical reaction has occurred in the fabric?
- b) Explain why removing the stain with bleach is not the same as rubbing it with water alone.
Changes of temperature: reactions that give out or take in heat
You touch a test tube in which you have just mixed two substances at room temperature and notice that it heats up strongly within seconds without having been put on a flame. Why do some mixtures change temperature by themselves without any external source of heat?
A basketball player sprains an ankle and the physiotherapist activates an instant cold pack by striking it: without a fridge or ice, the pack becomes freezing cold in…
A basketball player sprains an ankle and the physiotherapist activates an instant cold pack by striking it: without a fridge or ice, the pack becomes freezing cold in seconds. What observable change shows that an endothermic process is taking place inside the pack?
For the skiing trip, you take hand-warmer pouches that start heating up as soon as you open their plastic wrapper, without fire or batteries. a) What evidence of a…
For the skiing trip, you take hand-warmer pouches that start heating up as soon as you open their plastic wrapper, without fire or batteries.
- a) What evidence of a chemical reaction do they show?
- b) Reason why they cannot simply be "storing heat" from the factory.
In the laboratory, you mix two liquids that were each at $20\ \celsius$, and the thermometer in the mixture rises to $35\ \celsius$ without placing any Bunsen burner or…
In the laboratory, you mix two liquids that were each at $20\ \celsius$, and the thermometer in the mixture rises to $35\ \celsius$ without placing any Bunsen burner or hotplate near it, as shown in the diagram.
- a) What evidence of a chemical reaction is the thermometer detecting?
- b) Where has that heat come from if no one heated the mixture?
Emission of light
You light the candle on a birthday cake: while it burns, it gives off light and heats the surrounding air. Identify the two pieces of evidence of a chemical reaction…
You light the candle on a birthday cake: while it burns, it gives off light and heats the surrounding air. Identify the two pieces of evidence of a chemical reaction emitted by the burning candle.
At a concert, you bend a glow stick bracelet, it makes a "click" sound and begins to glow with green light, without batteries or a plug. a) What evidence of a chemical…
At a concert, you bend a glow stick bracelet, it makes a "click" sound and begins to glow with green light, without batteries or a plug.
- a) What evidence of a chemical reaction does the glow stick bracelet provide?
- b) A light bulb also gives off light and is not a chemical reaction: what is the difference between the two cases?
No single piece of evidence is enough on its own
Complete the sentence with the five main signs that reveal a chemical reaction: "Release of $\dots$, formation of a $\dots$ that settles at the bottom, change of…
Complete the sentence with the five main signs that reveal a chemical reaction: "Release of $\dots$, formation of a $\dots$ that settles at the bottom, change of $\dots$, variation in $\dots$ and emission of $\dots$."
The bathroom mirror steams up every time you take a hot shower. Is that evidence of a chemical reaction? Explain what is actually happening to the water vapour.
The bathroom mirror steams up every time you take a hot shower. Is that evidence of a chemical reaction? Explain what is actually happening to the water vapour.
When frying, the oil sizzles because water in the food evaporates suddenly; but if you leave it on the heat for too long, it starts to smoke, smell bad and turn black.…
When frying, the oil sizzles because water in the food evaporates suddenly; but if you leave it on the heat for too long, it starts to smoke, smell bad and turn black.
- a) Which sign of the process corresponds to a simple physical change?
- b) Which signs reveal that the oil is undergoing a chemical reaction? Justify both answers.
No single piece of evidence guarantees that a chemical reaction has taken place. Give a physical counterexample (an everyday phenomenon that shows the same sign without…
No single piece of evidence guarantees that a chemical reaction has taken place. Give a physical counterexample (an everyday phenomenon that shows the same sign without being chemical) for each of these four signs:
- a) A gas is given off.
- b) A solid appears where there was none before.
- c) The colour changes.
- d) The temperature changes.
Finish by explaining what you should always check, besides the sign, to confirm that a chemical reaction has occurred.
A freshly washed and thoroughly dried steel pot is placed over the blue flame of a gas stove: tiny droplets of water immediately appear on its base, which disappear…
A freshly washed and thoroughly dried steel pot is placed over the blue flame of a gas stove: tiny droplets of water immediately appear on its base, which disappear again as the pot heats up. The setup is shown in the figure:
- a) Where did that water come from if the pot was completely dry?
- b) Why are those droplets a clue that the combustion of the gas produces new substances?
- c) Why do they disappear afterwards? Classify this last process as physical or chemical.
Back to the beginning: You know that a new substance has formed with the vinegar and bicarbonate of soda because the gas produced puts out a lit match (a property different from that of the original air) and, when you evaporate the resulting liquid, you do not get back vinegar or bicarbonate of soda, but a different white salt (sodium acetate).