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BAC2 tech · Technology and Engineering II
Materials and manufacturing · Heat treatments and industrial manufacturing

Improvement treatments

The same ingot of steel can end up soft and easy to machine, or extremely hard and capable of cutting wood, depending on the cycle of heating and cooling it receives afterwards. The metal does not change composition: its internal structure changes, and with it, its mechanical properties.

Before you start, make sure you know: Classification of materials (1st Bachillerato)
Before you start, make sure you know: The properties of materials (1st ESO)

Quenching and tempering: hardness at the cost of brittleness

Quenching is the treatment that gives a steel the most hardness, but it is never used on its own: it is always followed by tempering, which corrects its main defect.

Graph of temperature against time comparing the sudden water-cooling path of quenching with the slow furnace cooling of annealing T t austenitising temperature quenching: rapid cooling (water) slow cooling (furnace)
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Describe the hardening process of a steel (approximate temperature, cooling medium and resulting microstructure) and explain what properties it gains and what drawback…

Describe the hardening process of a steel (approximate temperature, cooling medium and resulting microstructure) and explain what properties it gains and what drawback it introduces.

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The figure shows the cooling curves of two identical steel components: one is quenched in water and the other is left to cool inside the switched-off furnace. Indicate…

The figure shows the cooling curves of two identical steel components: one is quenched in water and the other is left to cool inside the switched-off furnace. Indicate which curve corresponds to hardening and explain what difference in hardness you expect between both components.

time t (min) temperature T (°C) curve 1 curve 2 850 ? which is hardening? 0
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After hardening, steels usually undergo tempering. Explain what tempering consists of, what problem from hardening it corrects, and why an untempered hardened tool would…

After hardening, steels usually undergo tempering. Explain what tempering consists of, what problem from hardening it corrects, and why an untempered hardened tool would be dangerous in service.

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Annealing and normalising: softening before working

Not all treatments aim to harden. Before machining or shaping a piece, the opposite is often needed: leaving it soft and free of stresses.

Graph of temperature against time: after heating the steel above the critical temperature, annealing cools very slowly inside the furnace and normalising cools more quickly in air; below, one piece in a furnace and another in open air Temperature time critical temperature annealing normalising annealing cools in the furnace maximum softening normalising cools in air quicker, somewhat harder
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Describe annealing: to what temperature the steel is heated, how it is cooled, and what effect it has on its hardness and internal structure. In what workshop situation…

Describe annealing: to what temperature the steel is heated, how it is cooled, and what effect it has on its hardness and internal structure. In what workshop situation is it applied before further working a component?

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Normalising cools in still air instead of inside the furnace. Compare annealing and normalising: which is faster and cheaper, which leaves the steel somewhat harder, and…

Normalising cools in still air instead of inside the furnace. Compare annealing and normalising: which is faster and cheaper, which leaves the steel somewhat harder, and what normalising is used for after forging.

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Order these cooling media from highest to lowest severity (cooling rate): oil, air, brine (salt water). Explain the relationship between the severity of the medium, the…

Order these cooling media from highest to lowest severity (cooling rate): oil, air, brine (salt water). Explain the relationship between the severity of the medium, the achievable hardness, and the risk of cracking or distortion.

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Surface treatments: hardness only where it is needed

Many pieces need a very hard surface (to resist wear) and a tough core (to absorb impacts without breaking). Treating the whole piece in the same way does not work: only the outer layer needs to be hardened.

Comparative cross-sections: on the left, a piece with a carburised or nitrided layer diffusing into a tough core; on the right, a base piece with a PVD or chrome coating deposited on its surface Thermochemical Coating core tough carburised/nitrided layer (diffusion of C or N) base piece PVD/chrome coating (deposited layer)
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Explain the basic idea of carburising: which element diffuses into the surface of the steel, at approximately what temperature it is performed, and why, after…

Explain the basic idea of carburising: which element diffuses into the surface of the steel, at approximately what temperature it is performed, and why, after carburising, the component must be hardened and tempered.

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Compare these three surface treatments: carburising, nitriding and hard chrome plating. For each one, indicate what is added or modified on the surface, a typical…

Compare these three surface treatments: carburising, nitriding and hard chrome plating. For each one, indicate what is added or modified on the surface, a typical application, and why it is beneficial to harden only the outer layer rather than the entire component.

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Compare a thermochemical treatment (carburising: modifies surface composition) with a hard PVD-type coating (deposited titanium nitride layer): typical thickness,…

Compare a thermochemical treatment (carburising: modifies surface composition) with a hard PVD-type coating (deposited titanium nitride layer): typical thickness, adhesion, process temperature, and an application where each is preferred (gears versus drill bits).

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Hardenability, TTT curves and residual stresses

Not all steels quench equally well, and quenching always leaves an aftermath: internal stresses that can distort or crack the piece if they are not controlled.

TTT diagram: rapid cooling avoids the pearlite start and finish curves and gives martensite; slow cooling crosses them and gives pearlite T log t Mₛ start finish rapid cooling: skips the curves → martensite slow cooling: crosses the curves → pearlite TTT curves (pearlite start/finish)
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TTT (time-temperature-transformation) diagrams show when the transformation of austenite starts and finishes upon cooling. Qualitatively explain why very rapid cooling…

TTT (time-temperature-transformation) diagrams show when the transformation of austenite starts and finishes upon cooling. Qualitatively explain why very rapid cooling "bypasses" the curves and produces martensite, whereas slow cooling passes through them and produces pearlite, which is softer.

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Define the hardenability of a steel and explain why a carbon steel only hardens in thin layers whereas an alloy steel (with chromium or molybdenum) through-hardens. What…

Define the hardenability of a steel and explain why a carbon steel only hardens in thin layers whereas an alloy steel (with chromium or molybdenum) through-hardens. What practical consequence does this have when choosing the steel for a thick shaft?

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After hardening, a long component has warped and another shows microcracks. Explain what residual hardening stresses are (cooling difference between surface and core),…

After hardening, a long component has warped and another shows microcracks. Explain what residual hardening stresses are (cooling difference between surface and core), how they cause distortion, and what process measures reduce them (uniform heating, less severe cooling media, component design).

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The energy and environmental cost of furnaces

Heat treatments require large masses of material to be kept at hundreds of degrees for hours: they are energy-intensive processes, and that carries an environmental cost that industry tries to reduce.

Comparison between heating a whole pinion in a furnace, where the entire piece is heated for hours, and heating it with an induction coil, which heats only the ring of teeth in seconds full furnace heats the whole piece hours, a lot of energy localised induction coil only the necessary area seconds, little energy
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A factory manufactures 1.000 drive shafts of 8,5 kg each per month. To ensure wear resistance on the bearing supports and cams, the production department compares two…

A factory manufactures 1.000 drive shafts of 8,5 kg each per month. To ensure wear resistance on the bearing supports and cams, the production department compares two alternatives:\n- Option A: Heating the entire part in a continuous gas furnace for 3,5 h at 870 °C, followed by full quenching and tempering in an electric furnace (equivalent energy consumption: 12,0 kWh per part).\n- Option B: Surface induction hardening localized exclusively on the bearing supports using a high-frequency inductor for 8 s with integrated spray quenching and self-tempering, keeping the core in its pre-normalized state (consumption: 1,4 kWh per part).\na) Justify from the mechanical behavior standpoint why Option B is preferable to Option A for a component subjected to fatigue and torsion.\nb) Calculate the annual energy savings (in kWh and percentage) that adopting Option B over Option A would entail.\nc) An environmental report states that "the greenest heat treatment is the one that consumes no energy, so all heat treatment should be eliminated." Refute this statement by evaluating the life cycle environmental impact of the steel if the absence of treatment reduces the part's service life to one quarter.

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In an industrial press, deep cylindrical casings are drawn from mild steel sheet (0,10 % C). The process requires two successive deep drawing strokes. When the two…

In an industrial press, deep cylindrical casings are drawn from mild steel sheet (0,10 % C). The process requires two successive deep drawing strokes. When the two operations are carried out consecutively without an intermediate stage, the sheet tears systematically on the second stroke, resulting in 100 % defective parts. The testing laboratory extracts a specimen after the first stroke and verifies that the yield strength has increased from 210 MPa to 550 MPa, while the elongation at break has dropped from 35 % to 3,5 %.\na) Interpret the tensile test results, explaining at the microstructural level the physical mechanism that has altered the steel's properties.\nb) Propose the specific heat treatment that must be inserted between both forming operations, justifying the appropriate operating temperature with respect to the critical points of the Fe-C diagram and the transformation experienced by the crystal grains.\nc) If incorporating the furnace for the intermediate treatment consumes 0,40 kWh per part (at a cost of 0,15 €/kWh) and each casing scrapped due to tearing represents a material and processing loss of 3,60 €, calculate above what percentage of defect reduction turning on the furnace becomes economically profitable.

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A batch of carbon steel threaded pins (0,50 % C) is heated to 850 °C in a muffle furnace with atmospheric air for 2 h before being quenched in oil. After tempering, the…

A batch of carbon steel threaded pins (0,50 % C) is heated to 850 °C in a muffle furnace with atmospheric air for 2 h before being quenched in oil. After tempering, the surface hardness test yields 32 HRC on the surface of the screw threads, but when sectioning the part and measuring at a depth of 0,6 mm, 52 HRC is obtained. Furthermore, the threads exhibit a rough scale that ruins the metric tolerances.\na) Explain, using the corresponding chemical reactions with the gases in the air, why this drop in surface hardness and the formation of scale at high temperature have occurred.\nb) Predict what mechanical failures the pin will suffer if it enters service installed in a vibrating machine subjected to alternating loads.\nc) Compare technically and economically two furnace solutions to prevent these two problems: controlled atmosphere furnaces (reducing or inert gas) versus vacuum furnaces, justifying which one you would choose if the production were high-volume with strict dimensional requirements.

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Summary

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