The atomic-molecular model
The law of conservation of mass describes what happens in a reaction, but it does not explain why it happens. Think about a campfire at a Fourth of July cookout: the logs shrink to a little ash, so where did the rest go? The answer came with one idea: all matter is made of atoms, and in a reaction those atoms do not disappear, they are simply rearranged.
Atoms that regroup
When an electric current is passed through liquid water, two different gases are obtained (hydrogen and oxygen), but the combined mass of the two gases is exactly equal to that of the water used up. How is it possible for one substance to turn into completely different ones without a single gram too many or too few?
According to the atomic-molecular model, elements are made of atoms, and these join together to form molecules. In a chemical reaction, the bonds between atoms are broken and new ones are formed, but the atoms themselves are neither created nor destroyed.
Complete the sentence with the missing words: 'According to the atomic-molecular model, all matter is made up of $\dots$. These group together to form $\dots$ and, in a…
Complete the sentence with the missing words: 'According to the atomic-molecular model, all matter is made up of $\dots$. These group together to form $\dots$ and, in a chemical reaction, they do not disappear: they simply $\dots$ to form new substances.'
When ice melts, the molecules remain $H_2O$; when water is decomposed by an electric current, $H_2$ and $O_2$ are produced. The figure shows the particles in both…
When ice melts, the molecules remain $H_2O$; when water is decomposed by an electric current, $H_2$ and $O_2$ are produced. The figure shows the particles in both processes.
Use the atomic-molecular model to explain which of the two changes is a chemical change and why.
Explain, using the atomic-molecular model, why mass is conserved in a chemical reaction (Lavoisier's law, also called the law of conservation of mass): what happens to…
Explain, using the atomic-molecular model, why mass is conserved in a chemical reaction (Lavoisier's law, also called the law of conservation of mass): what happens to the atoms during the reaction and what happens to their mass?
When water boils, the $H_2O$ molecules separate from one another, but do not break apart. a) Why is steam still water? b) What would have to happen to the molecules for…
When water boils, the $H_2O$ molecules separate from one another, but do not break apart.
- a) Why is steam still water?
- b) What would have to happen to the molecules for steam to stop being water?
Reading a chemical formula
A formula such as $H_2O$ is not just a name: it is an exact recipe showing which atoms, and how many, make up the molecule. Each letter is the symbol of an element, and you can find it on the periodic table: H is hydrogen (atomic number 1), C is carbon (6), N is nitrogen (7) and O is oxygen (8). Use the periodic table to find each symbol and atomic number.
The formula of water is $H_2O$. The figure shows its space-filling model. a) How many hydrogen atoms does a water molecule have? b) How many oxygen atoms? c) How many…
The formula of water is $H_2O$. The figure shows its space-filling model.
- a) How many hydrogen atoms does a water molecule have?
- b) How many oxygen atoms?
- c) How many atoms are there in total in the molecule?
The formula of carbon dioxide is $CO_2$. State which elements form its molecule and how many atoms of each element it contains.
The formula of carbon dioxide is $CO_2$. State which elements form its molecule and how many atoms of each element it contains.
Match each chemical symbol to its element: $H$, $O$, $C$ and $N$, with the names hydrogen, carbon, nitrogen and oxygen.
Match each chemical symbol to its element: $H$, $O$, $C$ and $N$, with the names hydrogen, carbon, nitrogen and oxygen.
Joined atoms and loose atoms
Writing $O_2$ is not the same as writing $2\ O$, even though both contain two oxygen atoms. The difference lies in whether they are joined together to form a molecule or are separate.
Look at the figure: Explain the difference between writing $O_2$ and writing $2\ O$: how many oxygen atoms are there in each case and how are they arranged (bonded…
Look at the figure:
Explain the difference between writing $O_2$ and writing $2\ O$: how many oxygen atoms are there in each case and how are they arranged (bonded together or separate)?
We want to build a model of the water molecule using modeling clay balls: we use red balls for the oxygen atoms and white balls for the hydrogen atoms. a) How many balls…
We want to build a model of the water molecule using modeling clay balls: we use red balls for the oxygen atoms and white balls for the hydrogen atoms.
- a) How many balls of each color do you need for a water molecule?
- b) Describe how the balls would be joined together.
In a ball model, black balls are carbon atoms, white balls are hydrogen atoms, and red balls are oxygen atoms. A black ball joined to four white balls represents…
In a ball model, black balls are carbon atoms, white balls are hydrogen atoms, and red balls are oxygen atoms. A black ball joined to four white balls represents methane, $CH_4$.
- a) Which molecule is represented by a black ball joined to two red balls?
- b) Describe the water molecule using the balls from this model.
In air, $N_2$ and $O_2$ molecules are separate and mixed together; in water, hydrogen and oxygen atoms are joined together forming $H_2O$ molecules, as shown in the…
In air, $N_2$ and $O_2$ molecules are separate and mixed together; in water, hydrogen and oxygen atoms are joined together forming $H_2O$ molecules, as shown in the figure.
Explain the difference between a mixture and a compound using the atomic-molecular model.
Balanced chemical equations
A chemical equation is a sentence written with formulas: the reactants on the left, the products on the right, and an arrow meaning "turn into". To obey the law of conservation of mass (Lavoisier's law), it has to be balanced: the same number of atoms of each element on both sides.
Move the coefficients until the table below says "balanced" for every element. Notice: the subscripts of a formula are never changed, only the coefficients in front.
Plants do this too. In photosynthesis, a leaf takes in carbon dioxide and water and makes glucose and oxygen: $6\ CO_2 + 6\ H_2O \rightarrow C_6H_{12}O_6 + 6\ O_2$. Count: 6 C, 12 H and 18 O on each side. The atoms are only rearranged. In a closed system, the total mass stays the same.
In the formation of water, two hydrogen molecules ($2\ H_2$) react with one oxygen molecule ($O_2$) to form two water molecules ($2\ H_2O$), as shown in the particle…
In the formation of water, two hydrogen molecules ($2\ H_2$) react with one oxygen molecule ($O_2$) to form two water molecules ($2\ H_2O$), as shown in the particle diagram.
Count the hydrogen and oxygen atoms before and after the reaction. Has any atom disappeared?
The combustion of methane is written as follows: $CH_4 + 2\ O_2 \rightarrow CO_2 + 2\ H_2O$. The diagram represents the molecules before and after. Count the atoms of…
The combustion of methane is written as follows: $CH_4 + 2\ O_2 \rightarrow CO_2 + 2\ H_2O$. The diagram represents the molecules before and after.
Count the atoms of each element before and after the reaction and verify that they are conserved.
A student writes the combustion of methane in their notebook as follows: $CH_4 + O_2 \rightarrow CO_2 + H_2O$. a) Count the atoms of each element on both sides of the…
A student writes the combustion of methane in their notebook as follows: $CH_4 + O_2 \rightarrow CO_2 + H_2O$.
- a) Count the atoms of each element on both sides of the arrow.
- b) Does their diagram respect the law of conservation of mass?
- c) Correct the equation so that the atoms balance and explain what you changed.
Counting atoms with coefficients
When an equation has coefficients and subscripts at the same time, you have to multiply them to count the atoms correctly.
Count carefully: a) How many hydrogen and oxygen atoms are there in $3\ H_2O$? b) How many carbon and oxygen atoms are there in $5\ CO_2$?
Count carefully:
- a) How many hydrogen and oxygen atoms are there in $3\ H_2O$?
- b) How many carbon and oxygen atoms are there in $5\ CO_2$?
The formula of ammonia is $NH_3$. a) How many atoms are there in an ammonia molecule? b) How many atoms of each element are there in $2\ NH_3$?
The formula of ammonia is $NH_3$.
- a) How many atoms are there in an ammonia molecule?
- b) How many atoms of each element are there in $2\ NH_3$?
The formation of water is represented as follows: $2\ H_2 + O_2 \rightarrow 2\ H_2O$. a) How many molecules are there before and after the reaction? b) How many atoms of…
The formation of water is represented as follows: $2\ H_2 + O_2 \rightarrow 2\ H_2O$.
- a) How many molecules are there before and after the reaction?
- b) How many atoms of each type are there before and after?
- c) Use the atomic-molecular model to justify the law of conservation of mass.
When an electric current is passed through water, it decomposes: $2\ H_2O \rightarrow 2\ H_2 + O_2$. The figure shows the experimental apparatus. a) Count the atoms of…
When an electric current is passed through water, it decomposes: $2\ H_2O \rightarrow 2\ H_2 + O_2$. The figure shows the experimental apparatus.
- a) Count the atoms of each element before and after.
- b) In the experiment, twice the volume of hydrogen is collected compared to oxygen: relate this to the number of molecules of each gas formed.
- c) Is mass conserved in this decomposition? Justify your answer.
The industrial synthesis of ammonia is written as: $N_2 + 3\ H_2 \rightarrow 2\ NH_3$. a) Design a model using balls (choose a color for each element) to represent this…
The industrial synthesis of ammonia is written as: $N_2 + 3\ H_2 \rightarrow 2\ NH_3$.
- a) Design a model using balls (choose a color for each element) to represent this reaction, before and after.
- b) Verify, by counting atoms in your model, that conservation of mass is respected.
- c) How many ammonia molecules are formed for each nitrogen molecule?
When a magnesium ribbon is burned in air, the oxide formed weighs more than the original ribbon. a) Explain this gain in mass using the atomic-molecular model. b)…
When a magnesium ribbon is burned in air, the oxide formed weighs more than the original ribbon.
- a) Explain this gain in mass using the atomic-molecular model.
- b) Predict what would happen to the total mass if we could also weigh all the air that took part in the reaction.
The formation of iron oxide can be written as: $4\ Fe + 3\ O_2 \rightarrow 2\ Fe_2O_3$. The diagram represents the atoms before and after. a) Count the iron and oxygen…
The formation of iron oxide can be written as: $4\ Fe + 3\ O_2 \rightarrow 2\ Fe_2O_3$. The diagram represents the atoms before and after.
- a) Count the iron and oxygen atoms before and after.
- b) An old, heavily rusted iron gate weighs more than when it was new: explain this using the atomic-molecular model.
- c) Where have the atoms that increase its mass come from?
Back to the start: The campfire logs don't vanish. Their carbon and hydrogen atoms join oxygen from the air and float away as carbon dioxide and water vapor. Mass is conserved because the atoms just change partners without being destroyed.