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Secondary 2 · Science II (Physics)
Energy · Heat

Effects of Heat on Matter

The metal lid of a jar of pickled jalapeños seems impossible to open, but it loosens by itself if you hold it under hot running water for a few seconds. And an ice cube turns into water and then into vapor if you give it enough heat. Heat doesn't just change temperature: it also changes the size and the state of matter. How and why? You're going to find out here.

Expansion

In summer, the cables that cross the street sag more than in winter, and a balloon gets tight if you bring it near a lit stove. Why do objects change size depending on their temperature?

The particle model explains this well: when heated, the particles vibrate or move with more energy and move slightly farther apart. The particles do not get bigger; what grows is the space between them.

Expansion of a solid, a liquid, and a gas with the same heating. Cold and hot: the metal ruler barely gets longer, the liquid rises somewhat in the flask tube, and the balloon placed over the flask of air swells a lot. solid (ruler) liquid gas (balloon) cold hot barely gets longer rises swells a lot Same heating: the solid barely expands, the liquid somewhat more and the gas much more. Dashed line: size when cold.

When heat arrives unevenly

An object doesn't always heat up evenly in all its parts. If you pour boiling water into a glass, the inner surface heats up and expands first, while the outer surface is still cold and hasn't expanded. This uneven expansion puts stress on the glass. If the stress is too great, the glass breaks.

In a thick glass, heat takes longer to pass through the wall, so the difference between the two surfaces lasts longer and is greater. That is why a thick glass breaks more easily than a thin one.

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What is thermal expansion? Explain it in your own words and give an everyday example where it can be observed, other than a thermometer.

What is thermal expansion? Explain it in your own words and give an everyday example where it can be observed, other than a thermometer.

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Between the rails of a train track there are small gaps every few meters. Observe the figure. a) What are these gaps for? b) What would happen to the rails on a very hot…

Between the rails of a train track there are small gaps every few meters. Observe the figure.

gap
  1. a) What are these gaps for?
  2. b) What would happen to the rails on a very hot day if the track did not have these gaps?
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If you suddenly pour boiling water into a thick glass, it may crack; in a thin glass it is less likely. Taking into account that the inner surface of the glass heats up…

If you suddenly pour boiling water into a thick glass, it may crack; in a thin glass it is less likely. Taking into account that the inner surface of the glass heats up and expands before the outer surface, explain why a thick glass breaks more easily.

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At Noa's house, the wooden door to the terrace rubs against the frame and is difficult to close in August, but in January it closes easily. a) Explain this using thermal…

At Noa's house, the wooden door to the terrace rubs against the frame and is difficult to close in August, but in January it closes easily.

  1. a) Explain this using thermal expansion.
  2. b) At what time of year will the door be slightly more "shrunk"?
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A metal bridge lengthens by $1\ \text{cm}$ for every degree its temperature rises. Look at the diagram of the bridge. a) Between a winter night at $0\ ^\circ\text{C}$…

A metal bridge lengthens by $1\ \text{cm}$ for every degree its temperature rises. Look at the diagram of the bridge.

expansion joint
  1. a) Between a winter night at $0\ ^\circ\text{C}$ and a summer afternoon at $35\ ^\circ\text{C}$, by how many degrees does the bridge's temperature rise?
  2. b) How many centimeters does the bridge lengthen between those two days?
  3. c) Will the expansion joints of the bridge be more open in winter or in summer? Give reasons for your answer.
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Changes of state

The ice in a michelada melts, puddles dry up when the Sun comes out, and steam fogs up the bathroom mirror. All of these are changes of state.

Why does it absorb or release heat? To separate the particles (melting, evaporating) you have to give them energy; when they come together again (condensing, freezing), that energy is released to the surroundings.

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When ice is heated, it turns into liquid water and, if heating continues, into steam. a) What is the change from solid to liquid called? b) What about the change from…

When ice is heated, it turns into liquid water and, if heating continues, into steam.

  1. a) What is the change from solid to liquid called?
  2. b) What about the change from liquid to gas?
  3. c) What are the two reverse changes called, those that occur when cooling?
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After the rain, puddles in the park disappear as soon as the Sun comes out. a) What change of state does the water in the puddles undergo? b) Where does the water get…

After the rain, puddles in the park disappear as soon as the Sun comes out.

  1. a) What change of state does the water in the puddles undergo?
  2. b) Where does the water get the heat needed for this change?
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When a candle is blown out, the melted wax next to the wick turns hard in a few minutes. a) What is the change of state that the wax undergoes called? b) In this change,…

When a candle is blown out, the melted wax next to the wick turns hard in a few minutes.

  1. a) What is the change of state that the wax undergoes called?
  2. b) In this change, does the wax absorb or release heat?
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When cooking pasta, the underside of the pot lid fills with small droplets of water. Look at the diagram. a) What happens to the steam when it touches the lid, which is…

When cooking pasta, the underside of the pot lid fills with small droplets of water. Look at the diagram.

steam droplets
  1. a) What happens to the steam when it touches the lid, which is cooler?
  2. b) What is this change of state called?
  3. c) When turning into droplets, does the steam absorb or release heat?
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When getting out of the shower, Nico feels cold even though the bathroom is warm. a) What change of state does the water remaining on his skin undergo? b) Where does…

When getting out of the shower, Nico feels cold even though the bathroom is warm.

  1. a) What change of state does the water remaining on his skin undergo?
  2. b) Where does this water get the heat it needs for the change?
  3. c) Use the previous answers to explain why it is advisable to dry oneself with a towel straight away.
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Seawater evaporates with the heat of the Sun; the steam rises, cools in the upper layers of the atmosphere and forms clouds; finally, rain falls. a) Name the change of…

Seawater evaporates with the heat of the Sun; the steam rises, cools in the upper layers of the atmosphere and forms clouds; finally, rain falls.

  1. a) Name the change of state that seawater undergoes when it turns into steam.
  2. b) Name the change of state that occurs when the cloud droplets form.
  3. c) In each of these two changes, does the water absorb or release heat? Who supplies it or takes it away?
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Temperature stays constant during a change of state

You put a pot of water on the stove and the thermometer rises and rises... until the water boils. Then it stays still at $100\ ^\circ\text{C}$ even if you turn up the flame. Where does the heat go?

Animation of the graph of temperature versus heat added: a point travels through the four segments from left to right; it rises in the ice and in the liquid water and moves horizontally, without rising, during melting and boiling. Each segment lights up together with its label. T heat added 0 °C 100 °C ice melting liquid water boiling

Each substance has its own temperatures

$0\ ^\circ\text{C}$ and $100\ ^\circ\text{C}$ are the melting and boiling temperatures of water. Other substances have their own. For example, mercury freezes at $-39\ ^\circ\text{C}$ and alcohol at $-114\ ^\circ\text{C}$. That is why at $-50\ ^\circ\text{C}$ mercury is already solid and its thermometer doesn't work, while alcohol is still liquid.

To know what state a substance is in, compare its temperature with its melting and boiling temperatures: below the melting point it is solid, between the two it is liquid, and above the boiling point it is a gas.

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An ice cube comes out of the freezer at $-10\ ^\circ\text{C}$ and we leave it on a plate in the kitchen. a) How high does the temperature of the ice rise before it…

An ice cube comes out of the freezer at $-10\ ^\circ\text{C}$ and we leave it on a plate in the kitchen.

  1. a) How high does the temperature of the ice rise before it starts to melt?
  2. b) What is the name of the change of state that it undergoes next?
  3. c) In this change of state, does the water absorb or release heat?
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Water freezes at $0\ ^\circ\text{C}$ and boils at $100\ ^\circ\text{C}$. State the state of matter of the water in each case and justify your answer. The diagram places…

Water freezes at $0\ ^\circ\text{C}$ and boils at $100\ ^\circ\text{C}$. State the state of matter of the water in each case and justify your answer. The diagram places the three cases on a temperature scale:

0 °C 100 °C a) −3 °C b) 25 °C c) 110 °C
  1. a) The water on the ice rink, which is at $-3\ ^\circ\text{C}$.
  2. b) The water in a glass, which is at $25\ ^\circ\text{C}$.
  3. c) The water coming out of a pot, which is at $110\ ^\circ\text{C}$.
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We slowly heat ice that is at $-10\ ^\circ\text{C}$ until it turns into steam at $110\ ^\circ\text{C}$, measuring the temperature the whole time. The setup is shown in…

We slowly heat ice that is at $-10\ ^\circ\text{C}$ until it turns into steam at $110\ ^\circ\text{C}$, measuring the temperature the whole time. The setup is shown in the diagram.

ice at −10 °C
  1. a) Make a list of the five stages of the process, indicating what is present in each stage (ice, water, steam or a mixture) and what the temperature is doing.
  2. b) In which two stages does the temperature not rise even though we continue to supply heat? At what temperatures do they occur?
  3. c) What is the heat being used for during those two stages?
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We put an ice cube tray filled with water into the freezer and measure its temperature every five minutes: $20\ ^\circ\text{C}$, $12\ ^\circ\text{C}$,…

We put an ice cube tray filled with water into the freezer and measure its temperature every five minutes: $20\ ^\circ\text{C}$, $12\ ^\circ\text{C}$, $5\ ^\circ\text{C}$, $0\ ^\circ\text{C}$… and for a long time it continues to read $0\ ^\circ\text{C}$ while the ice is forming. The graph shows the measurements.

5 10 15 20 25 30 5 10 15 20 T (°C) t (min)
  1. a) Your brother says that the water should go from $0\ ^\circ\text{C}$ to $-5\ ^\circ\text{C}$ continuously. Who is right, him or you? Why?
  2. b) While ice is forming, does the water continue to lose heat or not?
  3. c) What is that heat lost by the water during the change of state used for?
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Water, a special substance

Most substances take up less volume when they solidify, but water does the opposite: when it freezes it increases in volume. That is why ice is less dense than liquid water and floats.

Glass of liquid water with an ice cube floating in it: almost all of the ice is below the surface and only a small part sticks out, because ice is less dense than liquid water. ice (floats) less dense than water liquid water denser

Go back to the beginning: the lid of the jar opens because metal expands more than glass, and ice turns into water and vapor because the heat it receives rearranges its particles; while that happens, the temperature stays still.

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In the mountains, rainwater seeps into cracks in the rocks. At night it freezes and, little by little, the cracks get bigger until the rock eventually breaks. Look at…

In the mountains, rainwater seeps into cracks in the rocks. At night it freezes and, little by little, the cracks get bigger until the rock eventually breaks. Look at the diagram.

rock frozen water

Knowing that water increases in volume when it freezes, explain how it manages to break the rock.

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Water is an unusual substance: when it freezes its volume increases, so ice is less dense than liquid water. a) Explain why ice cubes float in a glass. b) In a lake in…

Water is an unusual substance: when it freezes its volume increases, so ice is less dense than liquid water.

  1. a) Explain why ice cubes float in a glass.
  2. b) In a lake in winter, does the surface freeze first or the bottom? Justify your answer.
  3. c) What advantage does this have for the fish living in the lake?
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At a scientific base in Antarctica, the thermometer reads $-50\ ^\circ\text{C}$. Mercury freezes at $-39\ ^\circ\text{C}$ and alcohol at $-114\ ^\circ\text{C}$. The…

At a scientific base in Antarctica, the thermometer reads $-50\ ^\circ\text{C}$. Mercury freezes at $-39\ ^\circ\text{C}$ and alcohol at $-114\ ^\circ\text{C}$. The diagram summarizes the data on a temperature scale.

0 °C mercury: −39 °C Antarctica: −50 °C alcohol: −114 °C
  1. a) Which thermometer works there, the mercury one or the alcohol one?
  2. b) What happens to the liquid in the other thermometer, making it unusable?
  3. c) What is the name of the change of state that this liquid undergoes?
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Summary

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