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Change · Change in material systems

Physical changes and chemical changes

On a frosty morning in Galway you leave the ice on your car windscreen to melt, and that evening you burn a piece of paper in the fire. In both cases something "disappears" in the form you knew it. But in only one of them can you get it back by cooling. What is the real difference between these two transformations?

Physical changes: the substance stays the same

You crumple aluminium foil, snap a piece of chalk in two or melt butter in a hot frying pan for your scones: their shape and state have changed completely, but are they still aluminium, chalk and butter?

An ice cube melts when heated and turns into liquid water in a glass; when cooled it solidifies again. Below, seen up close: the same H₂O molecules, ordered and fixed in the ice and disordered and moving, though still very close together, in liquid water. ice (solid) (when heated) melts solidifies (when cooled) liquid water ordered and fixed, vibrating in place disordered, sliding past and swapping places seen up close H₂O same substance, same molecules
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You leave a glass with ice cubes on the worktop and, after a while, they have turned into liquid water, as shown in the diagram. Has any new substance appeared? Is it a…

You leave a glass with ice cubes on the worktop and, after a while, they have turned into liquid water, as shown in the diagram.

ice liquid water

Has any new substance appeared? Is it a physical change or a chemical change? Justify your answer.

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You add a spoonful of salt to the water where you are cooking pasta, and the salt disappears from view, as shown in the diagram. Has it transformed into another…

You add a spoonful of salt to the water where you are cooking pasta, and the salt disappears from view, as shown in the diagram.

undissolved salt dissolved salt

Has it transformed into another substance? What do we call this type of change? How could you recover the salt?

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After disinfecting a cut with alcohol, the skin dries by itself in a few seconds because the alcohol evaporates. Has it stopped being alcohol? Classify the change and…

After disinfecting a cut with alcohol, the skin dries by itself in a few seconds because the alcohol evaporates. Has it stopped being alcohol? Classify the change and give reasons for your answer.

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In summer, the swimming pool needs to be topped up because the water slowly disappears, and new chlorine must also be added periodically because the previous chlorine…

In summer, the swimming pool needs to be topped up because the water slowly disappears, and new chlorine must also be added periodically because the previous chlorine has been consumed while disinfecting.

  1. a) Classify the two processes (losing water and chlorine being consumed) as physical or chemical.
  2. b) Why is the water topped up with a hose, but chlorine has to be bought again?
  3. c) Explain what would happen to the microorganisms in the water if chlorine did not transform into new substances when acting.
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Chemical changes: new substances appear

You can check this in the lab: measure the mass of everything before and after the change using a balance. For example, put water and an Alka-Seltzer tablet in a conical flask, seal it with a stopper (or put it in a closed bottle) and measure the total mass before and after the tablet fizzes. The reading is the same: in a closed container the total mass stays the same, so the new substances are made from the old ones, not from nothing. If you do it in an open flask, the reading drops, because the gas that forms escapes into the air. The mass has not disappeared; it has left the container. The same happens when paper burns in an open fireplace: the ash weighs less than the paper because the gases escape. Physical changes conserve mass too: if you weigh a sealed container of ice and weigh it again once the ice has melted, or weigh water before and after dissolving salt in it, the reading is unchanged, because no matter is created or destroyed. So the balance shows that mass is conserved in both kinds of change; to tell them apart you need to look for new substances.

Chemical change: a sheet of paper (reactant) burns and turns into ash, a new substance (product), while gases are given off. burns gases paper (reactant) ash (product: new substance)
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You burn some old papers in the fireplace and they are transformed into ash, smoke and heat. Is it a physical or chemical change? Could you recover the original paper in…

You burn some old papers in the fireplace and they are transformed into ash, smoke and heat. Is it a physical or chemical change? Could you recover the original paper in any way?

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A nail left outdoors on the balcony ends up covered in a reddish layer of rust. Is it a physical or chemical change? Explain what has happened to the iron in the nail.

A nail left outdoors on the balcony ends up covered in a reddish layer of rust. Is it a physical or chemical change? Explain what has happened to the iron in the nail.

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When frying an egg, the egg white, which was transparent and liquid, becomes white and solid. Is it a physical or chemical change? Could you get the raw egg back by…

When frying an egg, the egg white, which was transparent and liquid, becomes white and solid. Is it a physical or chemical change? Could you get the raw egg back by letting the pan cool down?

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Grandma's silver cutlery tarnishes over the years even though it is kept in a drawer. Is it a physical or chemical change? Explain what clue is given by the fact that…

Grandma's silver cutlery tarnishes over the years even though it is kept in a drawer. Is it a physical or chemical change? Explain what clue is given by the fact that this black layer cannot be removed by blowing or shaking.

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The criterion: new substances, not just appearance

Comparison at two scales. Physical change: ice melts and the H₂O molecules are the same, only their arrangement changes. Chemical change: wood burns and its molecules are transformed into new ones, such as CO₂ and H₂O, which form the smoke and the ash. same substances physical change new substances chemical change ice liquid water H₂O H₂O wood ash and smoke CO₂ and H₂O
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Complete the sentence and give an everyday example for each case: "In a physical change, no $\dots$ substances are formed, whereas in a chemical change, the initial…

Complete the sentence and give an everyday example for each case: "In a physical change, no $\dots$ substances are formed, whereas in a chemical change, the initial substances are transformed into $\dots$ substances with different properties."

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Think about these two kitchen situations: you freeze water to make ice cubes and then let them melt, and you toast a slice of bread until it turns golden brown. State…

Think about these two kitchen situations: you freeze water to make ice cubes and then let them melt, and you toast a slice of bread until it turns golden brown. State which of the two changes is reversible and which is not, and explain how this relates to whether they are physical or chemical.

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Your friend claims: "Water from a puddle evaporates under the sun and then falls back as rain; therefore, all changes are reversible and chemical changes do not exist."…

Your friend claims: "Water from a puddle evaporates under the sun and then falls back as rain; therefore, all changes are reversible and chemical changes do not exist."

  1. a) Give an everyday example, different from hers, that supports the first part of her reasoning.
  2. b) Give an example that proves her conclusion is false.
  3. c) Write a correct conclusion relating reversibility and the type of change.
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In a pottery workshop, Cian models a figure using wet clay (process A) and then bakes it in a kiln, so that it no longer softens even when wet (process B). a) Classify…

In a pottery workshop, Cian models a figure using wet clay (process A) and then bakes it in a kiln, so that it no longer softens even when wet (process B).

  1. a) Classify each process as physical or chemical.
  2. b) Justify your classification using the reversibility of each process.
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Aisha mixes plaster of Paris powder with water to make a figurine and, after a while, the mixture becomes hard as a rock. Compare this process with wetting sand at the…

Aisha mixes plaster of Paris powder with water to make a figurine and, after a while, the mixture becomes hard as a rock. Compare this process with wetting sand at the beach, which turns back into loose sand when it dries: which is physical and which is chemical? Justify your answer by considering whether the original material can be recovered.

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Changes of state, however dramatic they seem, are physical

Move the slider: the same substance goes from solid to liquid to gas as the temperature rises, and it is still the same substance the whole time. Dry ice is a special case: at normal air pressure it goes straight from solid to gas. This change of state, from solid directly to gas without passing through a liquid, is called sublimation.

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At concerts, dry ice is used, which is solid carbon dioxide at around $-78\ \celsius$: it leaves no puddle because it passes directly from solid to gas (invisible); this…

At concerts, dry ice is used, which is solid carbon dioxide at around $-78\ \celsius$: it leaves no puddle because it passes directly from solid to gas (invisible); this very cold gas makes the moisture in the air condense, forming that eye-catching fog. The diagram shows the possible changes of state; the orange arrow indicates the one dry ice undergoes:

? solid liquid gas
  1. a) What change of state does dry ice undergo?
  2. b) Is it a physical or chemical change? Explain why there is nothing left to "collect" at the end.
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You take a cold bottle out of the fridge and, after a while, it is wet on the outside, as shown in the diagram. Your cousin claims that the bottle is leaking and that…

You take a cold bottle out of the fridge and, after a while, it is wet on the outside, as shown in the diagram.

cold water air droplets on the outside

Your cousin claims that the bottle is leaking and that the water comes from inside. Explain what physical change actually occurs and where that water comes from.

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The tumble dryer heats the drum, the water in the damp clothes turns into steam and then a cold area of the appliance converts it back into liquid, which is collected in…

The tumble dryer heats the drum, the water in the damp clothes turns into steam and then a cold area of the appliance converts it back into liquid, which is collected in a reservoir. The diagram summarises the path of the water:

drum with damp clothes steam cold area reservoir
  1. a) Name the two changes of state that occur sequentially inside the tumble dryer.
  2. b) Are they physical or chemical? Justify your answer.
  3. c) Explain why it can be said that the water "has made a round trip" and what would happen if any of those changes were chemical.
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Chained processes: first physical, then chemical

Sometimes a physical change is just the preliminary step that makes a chemical change possible. You have to look at each stage separately.

Chained process: a liquid fuel evaporates (a physical change) and the resulting fuel gas burns (a chemical change), forming new substances such as CO₂ and water vapour. fuel liquid evaporates (physical) gas fuel burns (chemical) CO₂ and H₂O (new substances)
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To make a sponge cake, Nora melts chocolate in a bain-marie and, after mixing it with the other ingredients, bakes the batter. The diagram summarises the two processes:…

To make a sponge cake, Nora melts chocolate in a bain-marie and, after mixing it with the other ingredients, bakes the batter. The diagram summarises the two processes:

melting chocolate baking the batter
  1. a) Which of the two processes is a physical change and which is chemical?
  2. b) Give reasons for your answer by thinking about which of them could be "undone" by cooling.
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In a lighter, the liquid fuel in the reservoir turns into gas when exiting through the valve, and then this gas burns, producing the flame. The diagram summarises the…

In a lighter, the liquid fuel in the reservoir turns into gas when exiting through the valve, and then this gas burns, producing the flame. The diagram summarises the sequence of processes:

process 1 process 2 liquid butane butane gas flame

Identify the physical change and the chemical change that occur one after the other and explain how they differ.

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You heat sugar over low heat to make caramel: first it melts into a golden liquid; but if you get distracted, it darkens, gives off a burnt smell and ends up tasting…

You heat sugar over low heat to make caramel: first it melts into a golden liquid; but if you get distracted, it darkens, gives off a burnt smell and ends up tasting bitter.

  1. a) Which part of the process is a physical change?
  2. b) Which part is a chemical change and what signs give it away?
  3. c) Explain why liquid caramel, when cooled, becomes a sweet solid again, whereas there is no going back from burnt sugar.
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When you eat a sandwich, your teeth chop it up as you chew and then saliva and digestive juices in the stomach transform the food into new substances that the body can…

When you eat a sandwich, your teeth chop it up as you chew and then saliva and digestive juices in the stomach transform the food into new substances that the body can absorb.

  1. a) Identify the physical change and the chemical changes in the process.
  2. b) Explain why chopping alone would not be enough to nourish your cells.
  3. c) Is any of these changes reversible? Relate this to their classification.
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Cases that are hard to tell apart

Comparison between a pot of boiling water, where the water vapour condenses into drops under the cold lid (physical change, same substance), and a glass of water with an effervescent tablet giving off bubbles of carbon dioxide, a new gas (chemical change). cold lid water droplets water vapour (H₂O gas) CO₂ bubbles new gas water tablet boiling pot physical change H₂O comes out: the same substance effervescent tablet chemical change CO₂ forms: a new substance
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You heat water and, when it boils, huge bubbles rise. In another glass, you drop an effervescent tablet into cold water and bubbles rise everywhere as well, as shown in…

You heat water and, when it boils, huge bubbles rise. In another glass, you drop an effervescent tablet into cold water and bubbles rise everywhere as well, as shown in the diagram.

boiling water tablet in cold water
  1. a) In which of the two cases is there a chemical reaction?
  2. b) Steam from the saucepan, upon touching a cold lid, turns back into water droplets: what does this prove about the first situation?
  3. c) Explain why "bubbles appear" is not sufficient evidence to claim that a chemical change is taking place.
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In the laboratory, the teacher strongly heats a shiny metal ribbon inside a covered crucible and it turns into a whitish powder that no longer bends or conducts…

In the laboratory, the teacher strongly heats a shiny metal ribbon inside a covered crucible and it turns into a whitish powder that no longer bends or conducts electricity like the metal.

  1. a) Is it a physical or chemical change?
  2. b) Describe two tests you would perform to demonstrate that a new substance has been formed.
  3. c) Why is it not enough to say "its appearance has changed" to conclude that it is chemical?
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The batteries in the TV remote "run down" and have to be thrown away, whereas the mobile phone battery recharges every night and works again. a) What type of change…

The batteries in the TV remote "run down" and have to be thrown away, whereas the mobile phone battery recharges every night and works again.

  1. a) What type of change occurs inside a battery when it runs down?
  2. b) If the mobile phone battery "recovers" when recharged, does that mean a physical change occurs inside it? Reason your answer applying the criterion of new substances.
Solve

Back to the start: when the ice cube melts, the molecules are still water and cooling is enough to get it back (a physical change), whereas when the paper burns, the cellulose reacts and turns into ash, smoke and water vapour, new substances that do not form paper again when they cool (a chemical change).

Summary

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