Solutions
In an analytical laboratory nobody says "add a bit of salt": exactly $2{,}347\ \text{g}$ are weighed on a precision balance and a flask is filled up to a mark etched on the glass. That precision is not just a chemist's fussiness: a badly prepared solution gives a useless experimental result, a wrongly dosed medicine or a water analysis that fails to detect a pollutant. In this section you will treat solutions with that same rigour: three different ways of measuring how much is dissolved, how to convert from one to another, how they are really prepared and what happens, exactly, when they are mixed or diluted.
Three ways of expressing concentration
If you compare the label on a bottle of surgical spirit (70 % vol), a tub of hydrogen peroxide (3 % by mass) and a bag of saline solution (9 g/L), you will see that they all state how much solute they contain, but using completely different units: why isn't concentration always measured in the same way?
The same solution can be described in three different ways, depending on which two quantities are compared. Choosing the right one depends on whether the solute is a solid, a liquid or a gas, and on which piece of data is most practical to measure in each situation.
To fertilise her balcony plants, Nora dissolves $30\ \text{g}$ of soluble fertilizer in water to make $2\ \text{L}$ of solution. Mass concentration is calculated by…
To fertilise her balcony plants, Nora dissolves $30\ \text{g}$ of soluble fertilizer in water to make $2\ \text{L}$ of solution. Mass concentration is calculated by dividing the grams of solute by the litres of solution. What is the concentration of the fertilizer, in $\text{g/L}$?
To gargle, Marcos dissolves $5\ \text{g}$ of salt in $95\ \text{g}$ of water. a) How many grams of solution does he obtain in total? b) Percentage by mass is calculated…
To gargle, Marcos dissolves $5\ \text{g}$ of salt in $95\ \text{g}$ of water.
- a) How many grams of solution does he obtain in total?
- b) Percentage by mass is calculated by dividing the mass of solute by the total mass of solution and multiplying by $100$. What is the percentage by mass of salt?
A homemade hand sanitiser gel is prepared by mixing $30\ \text{mL}$ of alcohol with aloe vera to make up $150\ \text{mL}$ of gel. Percentage by volume is calculated by…
A homemade hand sanitiser gel is prepared by mixing $30\ \text{mL}$ of alcohol with aloe vera to make up $150\ \text{mL}$ of gel. Percentage by volume is calculated by dividing the volume of solute by the total volume of solution and multiplying by $100$. What is the percentage by volume of alcohol in the gel?
Preparing a solution in the laboratory
Calculating a concentration with a formula is only half the job: in a real laboratory that calculation has to be put into practice with specific instruments, and each step has a precise name.
In the laboratory, you are going to prepare $250\ \text{mL}$ of a solution using a volumetric flask. Put these steps in order and explain each one in your own words: a)…
In the laboratory, you are going to prepare $250\ \text{mL}$ of a solution using a volumetric flask. Put these steps in order and explain each one in your own words:
- a) Top up with water to the mark on the neck of the flask.
- b) Weigh the solute on the balance.
- c) Dissolve the solute in a beaker with a little water.
- d) Transfer the solution to the flask using a funnel and add water almost up to the mark.
What exactly does "topping up to the mark" mean?
You are asked to prepare $500\ \text{mL}$ of a copper sulphate solution with a concentration of $8\ \text{g/L}$. a) How many grams of copper sulphate should you weigh…
You are asked to prepare $500\ \text{mL}$ of a copper sulphate solution with a concentration of $8\ \text{g/L}$.
- a) How many grams of copper sulphate should you weigh out?
- b) Describe how you would prepare the solution in the laboratory, naming the apparatus you would use (balance, beaker, funnel, $500\ \text{mL}$ volumetric flask...) and at what point you top up to the mark.
Three classmates each prepare $250\ \text{mL}$ of a $10\ \text{g/L}$ solution by weighing $2,5\ \text{g}$ of salt, but each makes a mistake: a) Ioana does not tare the…
Three classmates each prepare $250\ \text{mL}$ of a $10\ \text{g/L}$ solution by weighing $2,5\ \text{g}$ of salt, but each makes a mistake:
- a) Ioana does not tare the balance with the watch glass, so she actually weighs out less salt than she thinks.
- b) Bruno tops up the flask above the mark on the neck.
- c) Carla transfers the solution to the flask but forgets to rinse the remaining salt stuck to the beaker with a little water.
For each case, explain what the error consists of and reason whether the actual concentration of their solution is above, below or equal to $10\ \text{g/L}$.
Density as a bridge between mass and volume
A commercial carboy of concentrated hydrochloric acid states "37 % by mass" on its label, but in the laboratory the liquid is not weighed: it is measured directly with a measuring cylinder in millilitres; how many grams of pure acid are you really pouring in every millilitre of solution?
Percentage by mass compares masses; concentration in g/L compares a mass with a volume. To convert from one to the other you need a piece of data that relates mass and volume: the density of the solution.
Percentage by volume appears mainly when the solute is itself a liquid or a gas: the air you breathe is a gaseous solution, with nitrogen as the solvent (the main component) and oxygen, argon and other gases as solutes.
Dry air is a solution of gases: $78\ \%$ of nitrogen, $21\ \%$ of oxygen and $1\ \%$ of argon and other gases, by volume. The figure summarizes this composition. a) What…
Dry air is a solution of gases: $78\ \%$ of nitrogen, $21\ \%$ of oxygen and $1\ \%$ of argon and other gases, by volume. The figure summarizes this composition.
- a) What is the solvent in air? Give reasons for your answer.
- b) Approximately how many litres of oxygen are there in $10\ \text{L}$ of air?
A surface disinfectant label states "$70\ \%$ alcohol by volume". How many millilitres of alcohol does a $250\ \text{mL}$ bottle of this disinfectant contain?
A surface disinfectant label states "$70\ \%$ alcohol by volume". How many millilitres of alcohol does a $250\ \text{mL}$ bottle of this disinfectant contain?
A salt solution has a density of $1,05\ \text{g/mL}$ and a concentration of $10\ \%$ by mass. a) What is the mass of $1\ \text{L}$ of this solution? b) How many grams of…
A salt solution has a density of $1,05\ \text{g/mL}$ and a concentration of $10\ \%$ by mass.
- a) What is the mass of $1\ \text{L}$ of this solution?
- b) How many grams of salt are in that litre?
- c) Express the concentration in $\text{g/L}$.
- d) Is a $10\ \%$ solution by mass the same as a $10\ \text{g/L}$ solution? Give reasons for your answer using the previous results.
Mixing and diluting solutions
In a laboratory you almost never work with the solution exactly as it comes from the factory: it has to be diluted to the concentration a protocol requires, or several different solutions have to be mixed in the same container. In both cases, what is always conserved is the mass of solute, never the concentration.
For mopping, you dilute $50\ \text{mL}$ of bleach at $40\ \text{g/L}$ in water to make $2\ \text{L}$ of solution. Look at the diagram of the dilution. a) How many grams…
For mopping, you dilute $50\ \text{mL}$ of bleach at $40\ \text{g/L}$ in water to make $2\ \text{L}$ of solution. Look at the diagram of the dilution.
- a) How many grams of hypochlorite are in those $50\ \text{mL}$ of bleach?
- b) What is the concentration of the solution in the bucket, in $\text{g/L}$?
- c) Explain why the mass of hypochlorite does not change when adding water, even though the concentration does.
You mix $200\ \text{mL}$ of a $30\ \text{g/L}$ salt solution with $300\ \text{mL}$ of another salt solution at $10\ \text{g/L}$ in the same container. Assume the final…
You mix $200\ \text{mL}$ of a $30\ \text{g/L}$ salt solution with $300\ \text{mL}$ of another salt solution at $10\ \text{g/L}$ in the same container. Assume the final volume is the sum of the two. The diagram shows the mixture.
- a) How many grams of salt does each solution provide?
- b) What is the concentration of the mixture, in $\text{g/L}$?
- c) Why is the final concentration not $20\ \text{g/L}$, the mean of the two concentrations?
You prepare solution A by dissolving $18\ \text{g}$ of salt in water to make $300\ \text{mL}$. Then you take $100\ \text{mL}$ of A, pour them into a flask and top up…
You prepare solution A by dissolving $18\ \text{g}$ of salt in water to make $300\ \text{mL}$. Then you take $100\ \text{mL}$ of A, pour them into a flask and top up with water to $400\ \text{mL}$: this is solution B.
- a) Calculate the concentration of A, in $\text{g/L}$.
- b) How many grams of salt are in the $100\ \text{mL}$ taken from A?
- c) Calculate the concentration of B from those grams.
- d) Check that you get the same result using the dilution formula, $c_1\cdot V_1=c_2\cdot V_2$, and explain why it works: what is always conserved when diluting?