Minerals: concept and classification
The ice in a glacier in Glacier National Park is a mineral; liquid water is not. Volcanic glass is not either, even when it is found inside a rock. And the graphite in a pencil and the diamond in a ring are, chemically, the same substance. To understand this we need a precise definition of a mineral and one key idea: the crystal structure.
What a mineral is
If you compare a piece of glacier ice, a fragment of volcanic glass (obsidian) and a pearl, all three are natural solids, but in geology only the ice is classified as a mineral: what atomic-scale and origin conditions does this definition require?
List the conditions a solid must meet to be considered a mineral and apply this criterion to decide whether glacier ice and fossil amber are minerals.
List the conditions a solid must meet to be considered a mineral and apply this criterion to decide whether glacier ice and fossil amber are minerals.
What is the difference between a mineral and a rock? Give an example of a rock formed by a single mineral and another formed by several different minerals.
What is the difference between a mineral and a rock? Give an example of a rock formed by a single mineral and another formed by several different minerals.
Distinguish between an isolated crystal and an aggregate or crystalline mass. Why do many quartz samples not show perfect faces?
Distinguish between an isolated crystal and an aggregate or crystalline mass. Why do many quartz samples not show perfect faces?
What is the difference between the essential minerals and the accessory minerals of a rock? Give an example of each in a granite.
What is the difference between the essential minerals and the accessory minerals of a rock? Give an example of each in a granite.
Crystal structure: polymorphism and isomorphism
What is the crystalline structure of a mineral and how is it manifested externally in the habit or shape of its crystals?
What is the crystalline structure of a mineral and how is it manifested externally in the habit or shape of its crystals?
Graphite and diamond are composed exclusively of carbon and yet their properties are opposite. Based on crystal structure, explain how this is possible (polymorphism).
Graphite and diamond are composed exclusively of carbon and yet their properties are opposite. Based on crystal structure, explain how this is possible (polymorphism).
What is an isomorphous series? Explain, using ion substitution in the crystal lattice, why olivine can vary in composition between forsterite ($\text{Mg}2\text{SiO}4$)…
What is an isomorphous series? Explain, using ion substitution in the crystal lattice, why olivine can vary in composition between forsterite ($\text{Mg}_2\text{SiO}_4$) and fayalite ($\text{Fe}_2\text{SiO}_4$).
The color of olivine varies from pale green to dark brown according to its iron content. Relate this variation to the isomorphism of the forsterite–fayalite series and…
The color of olivine varies from pale green to dark brown according to its iron content. Relate this variation to the isomorphism of the forsterite–fayalite series and explain why color is not an absolute diagnostic criterion.
Chemical-structural classification
When geologists chemically analyzed the more than 5,000 known minerals, geologists observed that almost all of them combine metal cations with a very small number of anions or anionic groups: what is the most coherent criterion for sorting them into homogeneous families?
Name one representative mineral of each of these chemical groups: carbonates, sulfates, sulfides, oxides, and halides.
Name one representative mineral of each of these chemical groups: carbonates, sulfates, sulfides, oxides, and halides.
Classify the following minerals according to their chemical group and state the characteristic anion of each group: quartz ($\text{SiO}2$), calcite ($\text{CaCO}3$),…
Classify the following minerals according to their chemical group and state the characteristic anion of each group: quartz ($\text{SiO}_2$), calcite ($\text{CaCO}_3$), pyrite ($\text{FeS}_2$), and gypsum ($\text{CaSO}_4 \times 2\ \text{H}_2\text{O}$).
The silicates
Biotite can be split with your fingers into extremely thin, flexible sheets, while quartz (the main mineral in the sand of Outer Banks beaches) scratches steel and breaks with curved conchoidal fractures, even though both are made of silicon and oxygen: how can the same chemical unit give rise to minerals with such different behaviors?
Silicates are the most abundant group of minerals in the Earth's crust. Look at the diagram: its basic unit appears on the left, and two linked units on the right.…
Silicates are the most abundant group of minerals in the Earth's crust. Look at the diagram: its basic unit appears on the left, and two linked units on the right. Explain what the $\text{SiO}_4^{4-}$ tetrahedron is, what each sphere represents, and why the ability of tetrahedra to share oxygen atoms gives rise to so many different silicates.
Mica, feldspar, amphibole, pyroxene, olivine, and quartz are all silicates. State what they have in common and name at least two subgroups of silicates according to the…
Mica, feldspar, amphibole, pyroxene, olivine, and quartz are all silicates. State what they have in common and name at least two subgroups of silicates according to the arrangement of their tetrahedra.
Micas cleave into extremely thin sheets. Relate this property to their phyllosilicate structure, in which the tetrahedra form sheets, and explain why they flake apart…
Micas cleave into extremely thin sheets. Relate this property to their phyllosilicate structure, in which the tetrahedra form sheets, and explain why they flake apart with a fingernail.
Pyroxenes and amphiboles are single-chain and double-chain inosilicates, respectively. Explain how this structural difference translates into different cleavage angles…
Pyroxenes and amphiboles are single-chain and double-chain inosilicates, respectively. Explain how this structural difference translates into different cleavage angles ($90°$ versus $60°$ and $120°$).
Quartz, a tectosilicate, lacks cleavage and breaks with conchoidal fracture. Explain why its three-dimensional network of tetrahedra makes it so resistant and compare it…
Quartz, a tectosilicate, lacks cleavage and breaks with conchoidal fracture. Explain why its three-dimensional network of tetrahedra makes it so resistant and compare it with calcite.
Garnet, staurolite and andalusite are typical minerals of metamorphic rocks. Explain why they are called "index minerals" and what information their presence in a schist…
Garnet, staurolite and andalusite are typical minerals of metamorphic rocks. Explain why they are called "index minerals" and what information their presence in a schist provides.
Index minerals
Garnet, staurolite and andalusite are index minerals: each forms only within a certain range of temperature and pressure during metamorphism. If you find one in a schist, you know roughly how intense the metamorphism was. For example, a schist from the Appalachians with garnet formed at higher temperature and pressure than a rock that only contains chlorite.
Back to the beginning: ice is solid, natural, inorganic and crystalline (a mineral); liquid water and glass have no ordered lattice. Graphite and diamond are polymorphs: same composition, different structure.